Bismuth (Bi) and silver (Ag) are used in increasing amounts and are consequently being emitted from various sources and showing high accumulation rates in soils when sewage sludge is applied on arable land. This study aimed to analyze the amounts of Bi and Ag in three cosmetic products (foundation, powder, and eye shadow) in order to study the flows in urban wastewater in Stockholm, Sweden. Analyses showed that Bi was present in very high concentrations (7,000 to 360,000 milligrams per kilogram) in one third of the analyzed foundation and powder samples, whereas Ag concentrations all were below the detection limit. These cosmetic products explained approximately 24% of the measured total Bi amounts per year reaching the WWTP (wastewater treatment plant), making cosmetics a major Bi source, whereas for Ag the corresponding contribution was <0.1% of the measured annual Ag amounts. The results were roughly adapted for Europe and the United States, estimating the Bi flows from cosmetics to WWTPs. On a global scale, these flows correspond to a non-negligible part of the world Bi production that, every year, ends up in sewage sludge, limiting the reuse of a valuable metal resource. From an environmental and resource perspective, foundations and powder products should be considered as significant sources of measured Bi amounts in sludge. This large Bi flow must be considered as unsustainable. For Ag, however, the three analyzed cosmetic products are not a significant source of the total Ag load to WWTPs. Keywords:bismuth cosmetics industrial ecology sewage sludge silver substance flow analysis Supporting information is available on the JIE Web site
Summary The importance of a circular economy is today widely accepted and advocated, but among the challenges in achieving this, we find difficulties in the implementation of legislation and policies designed to control various waste streams from society. The example used in this article is wood that has been treated with chromated copper arsenate (CCA), which, in Sweden, has been covered by the rules for hazardous waste since 2002. One year later, in 2003, a survey showed that only 42% to 50% of the expected amount of CCA waste could be traced to the public waste management system. An updated material flow analysis for 2010 revealed that the figure had increased to 73%, whereas the fraction of correctly treated CCA wood waste had increased from 11% to 35%. However, almost one third of the expected volume was still not tracable, and half of the amount that was correctly submitted was incinerated together with nontoxic waste fractions. This results in, for example, arsenic contamination of slag and fly ashes that prevents the further use of these residue products. So, despite legislative instruments, there is still an urgent need for an improved collection of hazardous wood waste, as well as better routines for identifying hazardous flows and separating them from nonhazardous ones. For a circular economy to be achievable, a key priority should be to reduce the gap between intended directions and legislation, on one hand, and activities in practice on the other.
In this study, a substance flow analysis (SFA) for copper (Cu) was conducted, in which the inflow, stock, and outflow (in the form of diffuse emissions to soil and water) for Stockholm were estimated for 2013 and compared with a previous study from 1995, hence allowing a discussion on changes over time. A large number of applications containing Cu were analyzed (including power cables, copper alloys, heavy electrical equipment, tap water systems, roofs, cars, various consumer electronics, wood preservatives, and contact cables for the railroad). The results show that the inflow of Cu to Stockholm has increased between 1995 and 2013, both in total and per person, mainly as the result of an increase in heavy electrical equipment, power cables, and cars. The stock remains relatively unchanged, whereas the outflow has increased. For the outflow, the emission increase from brake linings is of greatest quantitative importance, with an estimated 5.8 tonnes annual emission of Cu to the environment of Stockholm in 2013 compared to 3.9 tonnes in 1995. Given that increasing inflows of limited resources drive the global demand, continuous monitoring of flows through society and management of outflow routes are crucial, including improvement of national legislation and regional environmental plans as well as efforts to increase resource-use efficiency and recycling.
Silver (Ag) can be a problem for wastewater treatment plants (WWTP) and their capability to use sewage sludge as a soil fertilizer. Due to a high accumulation rate in soils, the levels of Ag in the incoming water at the WWTP must be reduced. This study aims to identify major diffuse emission sources in the technosphere through a comprehensive substance flow analysis of Ag in Stockholm, Sweden. Large inflows and stocks of Ag were present in electrical and electronic goods and appliances as well as in jewellery and silverware. The total inflow was 3.2 tonnes (4.2 g/person), the total stock was 100 tonnes (140 g/person) and the total outflow was 330 kg (430 mg/person). Major identified Ag sources with emissions ending up in the WWTP (total 26 kg, 34 mg/person) were food, amalgam and beauty products (via urine and faeces, 12 mg/person or 11% of incoming amount), and textiles (via washing, 17 mg/person or 16% of incoming amount). This study explains approximately 35% of the total 80 kg Ag in the incoming water at Henriksdal WWTP in Stockholm. Plastic, photography and beauty products were identified as possible sources of Ag that need to be examined further.
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