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The Greenland Ice Sheet is losing mass at a remarkable rate as a result of climatic warming.This mass loss coincides with the export of dissolved organic matter (DOM) in glacial meltwaters. However, little is known about how the source and composition of exported DOM changes over the melt season, which is key for understanding its fate in downstream ecosystems. Over the 2015 ablation season, we sampled the outflow of Leverett Glacier, a large land-terminating glacier of the Greenland Ice Sheet. Dissolved organic carbon (DOC) concentrations and DOM fluorescence were analyzed to assess the evolution of DOM sources over the course of the melt season. DOC concentrations and red-shifted fluorescence were highly associated (R 2 > 0.95) and suggest terrestrial inputs from overridden soils dominated DOM early season inputs before progressive dilution with increasing discharge. During the outburst period, supraglacial drainage events disrupted the subglacial drainage system and introduced dominant protein-like fluorescence signatures not observed in basal flow. These results suggest that subglacial hydrology and changing water sources influence exported DOC concentration and DOM composition, and these sources were differentiated using fluorescence characteristics. Red-shifted fluorescence components were robust proxies for DOC concentration. Finally, the majority of DOM flux, which occurs during the outburst and postoutburst periods, was characterized by protein-like fluorescence from supraglacial and potentially subglacial microbial sources. As protein-like fluorescence is linked to the bioavailability of DOM, the observed changes likely reflect seasonal variations in the impact of glacial inputs on secondary production in downstream ecosystems due to shifting hydrologic regimes.

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Proglacial lakes are effective sediment traps but their impact on the reliability of downstream sediment records to reconstruct glacier variability remains unclear. Here, we investigate the sedimentary signature of the recent recession of Steffen Glacier (Chilean Patagonia, 47°S) in downstream fjord sediments, with a focus on identifying the trapping (decreased downstream sediment yield) and filtering (removal of coarse particles) effectiveness of a growing intermediate proglacial lake. Four sediment cores were collected along a 14 km longitudinal transect in Steffen Fjord and the sediment physical and chemical properties were compared with aerial imagery at high temporal resolution. The caesium‐137 (137Cs) chronology of the most distal core and sediment trap data suggest that sediment accumulation in the fjord remained relatively stable through time, despite the accelerating glacier recession and the growth of Steffen proglacial lake. This is in contrast with many studies that indicate a decrease in sediment yield during proglacial lake expansion. It implies that the increase in sediment export due to accelerating meltwater production may be balanced by the sediment trapping effect of the growing proglacial lake. The fjord sediments show a slight fining upward accompanied by a marked decrease in flood‐induced grain‐size peaks, most likely due to the increasing filtering and dampening effect of the expanding proglacial lake. Our findings show that the filtering effect of the proglacial lake reached a threshold in 1985, when the lake attained an area of 2.02 km2. The additional 5 km of glacier recession during the following 32 years did not have any significant impact on downstream sedimentation. This study confirms that proglacial lakes act as sediment traps but it indicates that (1) the trapping effect can be outpaced by accelerating glacier recession and (2) the filtering effect becomes stable once the lake attains a certain critical size. © 2020 John Wiley & Sons, Ltd.

<p>The current climate trajectory in conjunction with agricultural intensification and the reliance on synthetic fertilisers, present further threat to the resilience of future food production through their contributions to soil degradation and consequent climatic feedback. Innovative sustainable agricultural technologies are needed to produce nutritious and equitable food products in line with the UN’s goal for Zero Hunger and sustainable development. Glacial Rock Flour (GRF) is a fine mineral rock dust, made available through the glacial abrasion of bedrock, and is often enriched in nutrients (e.g. Potassium, Phosphorous, Silicon, trace elements) but low in Nitrogen. It would therefore be a suitable soil fertility amendment for legume crops grown in acidic, nutrient poor soils often found in many mountainous regions (e.g. Hindu Kush Himalaya), where GRF is considered an alluvial ‘waste’ silting up dams and reservoirs. We have investigated the effect of GRF soil amendments in soil-plant mesocosms using a typical UK silt loam arable soil (pH~7) for cultivating red clover (<em>Trifolium pratense</em>) inoculated with <em>Rhizobium</em>. GRF from the Chhota Shigri (India) and Sólheimajökull (Iceland) glaciers were applied at 2 and 20 T/ha, while no GRF treatments included synthetic fertilizer applications of phosphorus (P), potassium (K) and P+K, and they were all compared against control red clover plants grown with no soil amendments. The nitrogen fixation capacity of red clover was estimated via <sup>15</sup>N natural abundance against a rye grass control (<em>Lolium perenne</em>) in two harvests on weeks 14 and 19. Both 20 T/ha GRF treatments appeared to stimulate fixed nitrogen yield compared to synthetic fertilizer treatments and control red clover plants, while the stimulation was more pronounced in the 2<sup>nd</sup> harvest as the soil nutrients were progressively depleted. Soil greenhouse gas fluxes over the growth period (weeks 4-14) were monitored by enclosing pots in sealed chambers. While no difference was observed in carbon dioxide fluxes between treatments, nitrous oxide (N<sub>2</sub>O) flux was negative for all red clover mesocosms with the N<sub>2</sub>O reduction being more prominent in both 20 T/ha GRF treatments towards the end of the first growth period (week 14). Gross N mineralization and nitrification were estimated in post-harvest soils from all the mesocosms using the isotope dilution method, while <sup>15</sup>N-N<sub>2</sub>O and <sup>15</sup>N-N<sub>2</sub> production were also measured after amending the soils with 98 at% <sup>15</sup>N-NH<sub>4</sub><sup>+</sup> and <sup>15</sup>N-NO<sub>3</sub><sup>-</sup><sub>. </sub> Gross N mineralization was not different between treatments, while nitrification was non-detectable, indicating a very tightly coupled N cycle between <em>Rhizobium </em>and red clover. However, when excess nitrate was applied, bacterial denitrification was active but the amendment of the soils with GRF appeared to reduce the production of N<sub>2</sub>O and promote complete denitrification to N<sub>2</sub>. Our novel study on the properties and application of GRF as a sustainable soil fertility amendment under a low nitrogen cropping system, holds promise that it can promote leguminous nitrogen fixation and a tightly-coupled N cycle that maximises N-use efficiency while mitigating N<sub>2</sub>O emissions by promoting complete denitrification.</p>

This work is licensed under a Creative Commons Attribution 4.0 International License Newcastle University ePrints-eprint.ncl.ac.uk

<p>Glacial Lake Outburst Floods (GLOFs) are an increasing threat to Patagonian environments and communities. Here, we investigate the geomorphological and hydrological impact of a recent GLOF from Pascua River, which discharges at the head of Baker Fjord (Chile, 48°S). To do so, a sediment core was taken ~4 km offshore of the Pascua River mouth at a water depth of 248 m. The coring site is located on the flank of a submarine channel incised trough the subaquatic delta of Pascua River, 30 m above the bottom of the channel. The sediment physical and chemical properties were analysed at high resolution with X-ray CT, MSCL and XRF core scanning, in combination with lower resolution grain-size and bulk organic geochemistry measurements, and a core chronology was established using downcore variations in <sup>137</sup>Cs activity. In addition, historical maps and satellite imagery of the past century were examined in combination with multibeam bathymetry of Baker Fjord to aid the interpretation of the sediment record.</p><p>Results show that the sediments are composed of two distinct units separated by a 5-cm thick event deposit dated 1945±9 CE. Below the event, the sediment consists of coarse silt and fine sand, likely representing sediment deposition from turbidity currents. Above it, it consists of very fine silts, likely representing settling from the surficial sediment plume. Historical evidence shows that the event deposit corresponds to a ~256 10<sup>6</sup> m<sup>3</sup> GLOF from Bergues Lake, the proglacial lake of Lucia Glacier that discharges directly into Pascua River. Before 1945, historical information shows that Pascua River drained via two active river branches that were most likely connected to the two submarine channels visible in the bathymetry of the subaquatic delta. After 1945, only the western river branch appears active, which likely caused the abandonment of the eastern submarine channel near which the sediment core was taken. Therefore, we hypothesize that the 1945 Bergues Lake GLOF caused the abandonment of the eastern river branch and submarine channel, which explains the absence of coarse-grained sediments in our sediment record after 1945±9 CE.</p><p>This study provides the first report of a GLOF from the northeastern part of the Southern Patagonian Icefield, and it demonstrates that GLOFs can have long-term impacts on the hydrology of fjord-river systems.</p>

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