Synthesizing lignin-based copolymers would valorize a major coproduct stream from pulp and paper mills and biorefineries as well as reduce the dependence on petrochemical-based consumer goods. In this study, we used organosolv lignin isolated from hybrid poplar ( Populus trichocarpa × P. deltoides) to generate lignin-containing methacrylate hydrogels. The copolymer hydrogels were synthesized by first grafting 2-hydroxyethyl methacrylate (HEMA) onto lignin (OSLH) via esterification and then by free radical polymerization of OSLH with excess HEMA. The copolymer hydrogels were prepared with different stoichiometric ratios of OSLH (e.g., 0, 10, 20, and 40 wt %) with respect to HEMA. Copolymerization with OSLH led to an increase in cross-linking density, which in turn enhanced the hydrogel's material properties; we report up to 39% improvement in water retention, 20% increase in thermostability, and up to a 3 order increase in magnitude of the storage modulus ( G'). The copolymer's properties, such as water retention and glass transition temperature, could be tuned by altering the percent functionalization of lignin OH groups and the ratio of OSLH to HEMA.

In this work, FeB, NiB, and FeNiB nanomaterials were examined as catalysts for catalytic transfer hydrogenolysis (CTH) using supercritical ethanol (sc-EtOH) as the hydrogen donor and reaction solvent. The earth-abundant alloys were synthesized using simple aqueous chemical reductions and characterized using ICP-OES, XRD, and STEM-EDS. Using acetophenone to model the desired catalytic reactivity, FeNiB was identified as having superior reactivity (74% conversion) and selectivity for complete deoxygenation to ethylbenzene (84%) when compared to the monometallic materials. Given its high reactivity and selectivity for deoxygenation over ring saturation, FeNiB was screened as a lignin valorization catalyst. FeNiB mediates deoxygenation of aliphatic hydroxyl and carbonyls in organosolv lignin via CTH in sc-EtOH. A combination of gel permeation chromatography, GC/MS, and NMR spectroscopy was used to demonstrate the production of a slate of monomeric phenols with intact deoxygenated aliphatic side chains. In total, these results highlight the utility of CTH for the valorization of biorefineryrelevant lignin using an inexpensive, earth-abundant catalyst material and a green solvent system that can be directly derived from the polysaccharide fraction of lignocellulosic biomass.

Lutherans have a reputation for not attending well to the life of sanctification. Whether or not this is deserved, it is clear that all believers should make greater efforts to live in conformity with the will of God. Distinctly lacking in the Lutheran heritage, however, are disciplines of self-cultivation. Such methods could play a larger role in the spiritual lives of believers, not for the sake of one's own salvation, but for the benefit of others. With that in mind, this article considers the practice of shugyō in Japanese Buddhism. This concept of self-cultivation can form a model for how we in the West might seek to attend to our own maturing in the Christian life, attending to a greater stewardship of our bodies and minds.

The union of divine and human in Jesus Christ was codified at the Council of Chalcedon. However, while this position makes good theological sense, in terms of soteriology, it remains a conceptual problem. How do two distinct entities combine into a single entity without the loss of their respective distinctiveness? This article recommends a move from a Greek metaphysic of “substance” to a Buddhist understanding of selfhood as emptiness. By understanding the self as an interweaving of multiple energies, rather than a fixed substance, Chalcedonian Christology can retain its soteriological integrity with a more helpful conceptual understanding of how two may become one.