This paper continues to address the overarching goal to provide a more unified understanding of NiTi shape memory alloys intended for use in structural applications by attempting to link standard processing practice and basic materials characterization to the deformation behavior of large diameter bars. Results from cyclic tensile tests performed on large diameter Ni-rich polycrystalline NiTi bars are presented. Coupon specimens taken from deformation processed bars with diameters of 12.7, 19.1, and 31.8 mm are tested along with their respective full-scale specimens. The coupon tests results reveal small and highly variable differences between specimens taken from the different size bars. The full-scale specimen tests continue to show the presence of the R phase, but lack a Lüders-like transformation. A comparison of the results suggests that coupon specimens provide only limited information in terms of the full-scale behavior. Full-scale tests using an earthquake-type loading then show similar behavior to the tensile cyclic tests suggesting the ability to use NiTi in structural applications. Overall, this paper and Tyber et al. 2007 provide a multiscale analysis of NiTi shape memory alloys to be used by both material scientist and civil engineers in the development of applications for NiTi.
We examine the structure and properties of cold drawn Ti-50.1 at % Ni and Ti-50.9 at % Ni shape memory alloy wires. Wires with both compositions possess a strong <111> fiber texture in the wire drawing direction, a grain size on the order of micrometers, and a high dislocation density. The more Ni rich wires contain fine second phase precipitates, while the wires with lower Ni content are relatively free of precipitates. The wire stress-strain response depends strongly on composition through operant deformation mechanisms, and cannot be explained based solely on measured differences in the transformation temperatures. We provide fundamental connections between the material structure, deformation mechanisms, and resulting stress-strain responses. The results help clarify some inconsistencies and common misconceptions in the literature. Ramifications on materials selection and design for emerging biomedical applications of NiTi shape memory alloys are discussed.
Whereas cellulose-derived polymers are routinely used as membrane materials, the cellulose polymer itself is not directly used to synthesize dense/porous films for membrane applications. Recently, N-methylmorpholine N-oxide (NMMO) and dimethylacetamide (DMAc)/lithium chloride (LiCl) have been successfully employed for dissolving unmodified cellulose. This provides a strong rationale for reexamining the possibility of cellulose membrane fabrication using these solvents. By judiciously selecting solvents, casting conditions, and solvent exchange steps, we successfully synthesized dense/ asymmetric-porous cellulose films. The pore size and porosity of the porous films decreased systematically with increasing cellulose concentration. SEM analysis of the cross sections revealed an asymmetric skinned structure with monotonically increasing pore size away from the skin. The measured pore diameters were in the range 1.8-4.8 mm. Mechanical testing indicated that the dense films possessed tensile properties comparable to those of cellulose acetate (CA) films. Though nitrogen permeability values were comparable for cellulose and CA dense films, cellulose film permeability depended upon the type of drying protocol employed. Overall, these results demonstrate that processability need not be a constraint in the use of cellulose polymer for membrane fabrication. In selected applications, cellulose membranes could become a cost-effective, environmentally friendly alternative to other more commonly employed membrane polymers.
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