This paper presents a multi-proxy reconstruction of the climatic and environmental changes during the Last Glacial-Interglacial transition as recorded by a sediment sequence from Lake Lautrey (Jura, eastern France). This reconstruction is based on analysis of pollen, chironomid, organic matter, oxygen-isotope, mineralogical, magnetic susceptibility and inferred lake-level data at a high temporal resolution. The chronology is derived using AMS radiocarbon dates, the position of the Laacher See Tephra (LST), and of correlation between the Lautrey and GRIP oxygen-isotope records. This data set reveals a detailed sequence of environmental changes in the Jura mountains from Greenland Stadial 2a to the early Holocene. Biotic and abiotic indicators allow the recognition of major abrupt changes associated with the GS2a/GI-1e, GI-1a/GS-1 and GS-1/Preboreal transitions, and other minor fluctuations related to the cold events GI-1d, GI-1b and the Preboreal oscillation (PBO). They also suggest additional cooling spells at ca 14,550 and 14,350 cal yr BP (Intra-Bølling Cold Periods), at ca 13,500 and ca 12,700 cal yr BP just before the GS-1 onset, and at ca 11,350 cal yr BP just before the PBO, as well as an intriguing brief warming episode within GS-1 at ca 12,080 cal yr BP. Summer temperature increased by ca 5 °C at the start of GI-1e, and by 1.5-3 °C at the Holocene onset, while it decreased by ca 3-4 °C at the beginning of GS-1. Major changes in local hydrology and in seasonality appear to be also associated with the GS-2a/GI1e, GI-1a/GS-1 and GS-1/Preboreal transitions. Pollen and abiotic indicators suggest a greater sensitivity of the vegetation cover to climatic oscillations during the first part of the Lateglacial Interstadial than during the second part (after ca 13,700 cal yr BP), when a closed forest had been restored in this area. By contrast, the restoration of forest cover took less than 300 yr after the end of GS-1. At the beginning of GI-1e and GS-1, no lag occurs (within the sampling resolution of 20-50 yr) in the responses of aquatic (chironomids) and terrestrial (pollen) ecosystems, while, at the onset of the Holocene, the response of the vegetation appears slightly delayed in comparison with that of the chironomid community. Finally, the recognition of two successive tephra layers, which were deposited just before the LST at ca 12,950 cal yr BP and which originated from Le Puy de la Nugère (Massif Central, France), provides an additional tephrochronological tool for correlation between Lateglacial European sequences.
The Lüderitz upwelling cell is presently the most productive area of the Benguela current system and abundant organic matter (OM) accumulates on the adjacent slope sediments even at great water depth. OM from two cores taken on the slope and covering the last 280 kyear was analysed in terms of "petroleum quality" (Rock-Eval), chemical features (FTIR, EDS) and petrographic composition (light microscopy and TEM). These data indicate that the OM is more oxidized at 3606 m water depth than on the upper slope sediments (1029 m) although the petroleum quality of the OM throughout the deep-water core remains surprisingly high for hemipelagic deepsea sediments (HI=200-400 mg/g). The petroleum quality of OM accumulated on the upper slope is consistently high: HI averages 450 mg/g. Two petrographic types of OM are distinguishable from microscopic observation, each ascribed to distinctive preservation mechanisms: (1) 'Granular' amorphous OM, which dominates in the deep-water core, is formed by organo-mineral aggregates. Aggregation appears to be the primary preservation mode at this depth although is quantitatively limited (maximum TOC value of 4 wt.% of bulk sediment obtained through this process). The ultrastructure of the aggregates highlights an intimate association pattern between sedimentary OM and clays. (2) 'Gel-like' nannoscopically amorphous OM (NAOM) largely dominates at 1000 m water depth and contains sulfur. Thus, early diagenetic sulfurization was probably involved in the preservation of this OM, but a contribution from the classical degradation-recondensation pathway cannot be ruled out. Moreover, selective preservation occurred at both sites but represents an insignificant part of the OM. Organic fluxes mainly control the occurrence and extent of sulfurisation at both water depths by determining the redox conditions at the sea floor. Aggregate formation is limited by both organic and mineral fluxes at the lower slope whereas OM supply is never limiting on the upper slope. Although consistently operating through time at both depths, preservation by organo-mineral association is limited by mineral availability and thus accounts for a relatively minor portion of the OM accumulated on this organic-rich slope. In the case of large organic fluxes, sulfurisation and/or degradation-recondensation is required to obtain TOC contents above 4 wt.% of bulk sediment in the area.
Geochemical analysis of sedimentary organic matter in recent lacustrine sediments appears to be a useful tool in providing information concerning past environmental conditions. However, such analysis is often made without knowing the geochemical characteristics of the organic matter derived from the watershed and, more explicitly, its soils. The present work deals with (i) a geochemical investigation (Rock-Eval pyrolysis) of soil organic matter sampled in a lake watershed, and (ii) the study of the sedimentary organic matter trapped in the lake deposits. The research was conducted on Chaillexon Lake which was created by a rock collapse that dammed the palaeovalley of the Doubs River about 12 000 years ago. Since this event, the sediment trap provides a continuous palaeoclimatic record for the Postglacial period.Results obtained lead to two main conclusions. First, the variability of Rock-Eval pyrolysis values observed in soils modifies the common interpretation given to these parameters in the characterization of sedimentary organic matter. Indeed, variations in these parameters point not only to varying proportions of terrestrial and lacustrine organic matter in a lacustrine infilling but also to variations of the terrestrial supply linked with the evolution of vegetal cover in the catchment. The second conclusion is that the story of the Chaillexon lacustrine system is marked by a rather sudden soil and forest development at the Preboreal-Boreal transition (9000 BP).
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