This shows that the convective heat transfer from the flame is the main contribution to sustain the pyrolysis process and the flame spread is mainly ensured owing to the combined contribution of convection from flame and conduction inside the condensed phase. The maximum incident radiative flux along the molten ball is 17.5 kW/ m 2 and is reached at the molten ball trailing edge whereas the radiant fraction is about 0.25. Neglecting flame self-absorption affects these values by less than 5%, showing that the optically-thin approximation is valid for this flame. In addition, soot radiation dominates the radiative heat transfer in this flame, contributing for about two-third of the total radiation. Finally, model results show that the usuallyused thermally-thin assumption throughout the LDPE coating is not strictly valid.

A new optical setup and its associated post-processing have been designed in an effort to map soot related quantities in an axisymmetric flame spreading over solid samples in microgravity environment where setup compactness constraints are stringent. Extending the well-established spectral modulated absorption/emission (S-MAE) technique that uses lasers as light sources together with a sophisticated optical arrangement, LEDs have been associated with broadband optics to enable the broadband modulated absorption/emission (B-MAE) technique. The design and the cautious assessment of the original B-MAE setup are reported in the present paper. Algorithms that need to be reformulated for broadband integration are first validated retrieving both two-dimensional soot temperature and volume fraction fields produced by numerical simulations. Then, these fields are measured with both B-MAE and S-MAE techniques in a largely documented steady laminar non-premixed coflow ethylene/air flame established at normal gravity. Thus, outputs delivered by the B-MAE technique can be compared with those obtained with the S-MAE setup. Both soot temperature and volume fraction are shown to be decently measured by the B-MAE technique. As the spread of the non-buoyant flames to be investigated in the near future is especially driven by radiative heat transfer, the discrepancies between both techniques outputs are commented in the light of the fields of local radiative loss computed from the fields measured by both techniques. As a result, the fields delivered by the B-MAE technique are expected to provide ground-breaking insights into the control of flame spread in the absence of buoyancy, therefore manned spacecraft fire safety.

We investigate the kinetic theory of two-temperature plasmas for reactive polyatomic gas mixtures. The Knudsen number is taken proportional to the square root of the mass ratio between electrons and heavy-species, and thermal non-equilibrium between electrons and heavy species is allowed. The kinetic non-equilibrium framework also requires a weak coupling between electrons and internal energy modes of heavy species. The zeroth-order and first-order fluid equations are derived by using a generalized Chapman-Enskog method. Expressions for transport fluxes are obtained in terms of macroscopic variable gradients and the corresponding transport coefficients are expressed as bracket products of species perturbed distribution functions. The theory derived in this paper provides a consistent fluid model for non-thermal multicomponent plasmas.

In this paper, we use a fluid model to simulate the excitation of a hydrogen radio-frequency discharge, and employ tailored voltage waveforms to assess the effect of charged species transport properties. Results of the fluid simulation are compared with experimental data and previous results obtained with a hybrid model. Several expressions for electron and ion transport coefficients are compared, and their impact on the self-bias potential is studied. The self-bias is shown to be insensitive to the choice of electron transport coefficients, while remarkably sensitive to variations in ion mobility. Besides, our results show that fluid models can be competitive with hybrid models, provided self-consistent ion transport models and rate constants are used.

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In most simulations of fine particles in reacting flows, including sooting flames, enthalpy exchanges between gas and particle phases and differential diffusion between the two phases are most often neglected, since the particle mass fraction is generally very small. However, when the nanoparticles mass fraction is very large representing up to 50 % of the mixture mass, the conservation of the total enthalpy and/or the total mass becomes critical. In the present paper, we investigate the impact of mass and enthalpy conservation in the modeling of titania nanoparticles synthesis in flames, classically characterized by a high conversation rate and consequently a high nanoparticles concentration. It is shown that when the nanoparticles concentration is high, neglecting the enthalpy of the particle phase may lead to almost 70 % relative error on the temperature profile and to relative errors on the main titania species mass fractions and combustion products ranging from 20 % to 100 %. It is also established that neglecting the differential diffusion of the gas phase with respect to the particle phase is also significant, with almost 15 % relative error on the TiO2 mole fraction, although the effect on combustion products is minor.

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