Miners around Zimbabwe used to supply gold concentrates from sulphide flotation to the Kwekwe Roasting Plant (Zimbabwe) for toll treatment. The concentrates were roasted in Edward’s roasters and the calcine product was leached by cyanidation. Due to inefficient roasting, overall gold recoveries of 75–80% left behind a rich calcine leach residue at the Kwekwe Roasting Plant. The characterization performed to establish a potential process route involved several techniques, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), fire assaying and inductively coupled plasma (ICP). Assays conducted on samples from the 350,000 tons tailings dam residue, created over the operational years, gave an average Au grade of 8.58 g/t and 12.54 g/t for Ag. The base metals assayed—0.11% Cu, 0.10% Pb, 0.17% Zn and 26.05% Fe. SiO2 (36.1%), Fe2O3 (36.9%), Mg3Si4O10 (OH)2 (8.9%), NaAlSi3O8 (6.9%), and Fe3O4 (6.4%)—were the major mineral phases in the cyanide leach residue. SEM gold scans on 24 polished sections showed only 2 discrete gold particles of less than 5 µm, with one partially liberated and associated with quartz, while the other was fully liberated. Therefore, the particulate gold in the calcine leach residue was negligible. It was deduced from the analysis after ultrafine milling (P80 < 5 µm) followed by cyanidation that 68.53% of the gold was sub-microscopic. Direct cyanidation using bottle roll resulted in only 2.33% of the total gold being leachable, indicating that the calcine leach residue was highly refractory. Diagnostic leaching by sequential use of acids in order of their strength resulted in HCl leachable phases (CaCO3, CaMg(CO3)2, PbS, Fe1-XS, and Fe2O3) freeing 4.2% of the total Au during subsequent cyanidation leach. H2SO4 leachable phases (Cu–Zn sulphides, labile FeS2) released an additional 26.57% during cyanidation, whereas HNO3 leachable phases (FeS2, FeAsS) released a further 20.98% of Au. After acid treatment and subsequent cyanidation, hot caustic leach of the residue followed by carbon in pulp resulted 4.43% of the total gold being eluted. Therefore, 4.43% of the total gold was surface bound. From the analysis after diagnostic acid leaching, it was deduced that a total of 54.08% of the gold was in the acid-leachable phase. Due to cost and environmental considerations, H2SO4 was selected for the evaluation of acid digestion as a pretreatment stage followed by cyanidation. Increasing the H2SO4 strength for the pretreatment of the calcine leach residue increased gold recoveries during cyanidation.
The cyanidation process for refractory gold ores has been the subject of numerous investigations aimed at improving gold recovery and leaching kinetics. From recent literature investigations, hydrodynamic cavitation has been found to be a promising new approach which may modify the cyanidation processes. In this study, this approach results in the enhancement of mass transfer kinetics in multiphase fluid streams due to impacting two pulps streams against one another in a vessel called the Jetleach reactor. In this work, the Jetleach reactor was applied to a flotation concentrate from a South African gold tailings processing plant (Ergo) where an improvement of almost 10% in gold recovery was obtained while decreasing cyanide and oxygen consumption by almost 8% and 50%, respectively. The main reason for the improvement is surmised to be due to the generation of micro-cavitation which improves the mass transfer of oxygen and cyanide within the slurry.
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