The composition of the neutral gas comas of most comets is dominated by H2O, CO and CO2, typically comprising as much as 95 per cent of the total gas density. In addition, cometary comas have been found to contain a rich array of other molecules, including sulfuric compounds and complex hydrocarbons. Molecular oxygen (O2), however, despite its detection on other icy bodies such as the moons of Jupiter and Saturn, has remained undetected in cometary comas. Here we report in situ measurement of O2 in the coma of comet 67P/Churyumov-Gerasimenko, with local abundances ranging from one per cent to ten per cent relative to H2O and with a mean value of 3.80 ± 0.85 per cent. Our observations indicate that the O2/H2O ratio is isotropic in the coma and does not change systematically with heliocentric distance. This suggests that primordial O2 was incorporated into the nucleus during the comet's formation, which is unexpected given the low upper limits from remote sensing observations. Current Solar System formation models do not predict conditions that would allow this to occur.

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The provenance of water and organic compounds on Earth and other terrestrial planets has been discussed for a long time without reaching a consensus. One of the best means to distinguish between different scenarios is by determining the deuterium-to-hydrogen (D/H) ratios in the reservoirs for comets and Earth's oceans. Here, we report the direct in situ measurement of the D/H ratio in the Jupiter family comet 67P/Churyumov-Gerasimenko by the ROSINA mass spectrometer aboard the European Space Agency's Rosetta spacecraft, which is found to be (5.3 ± 0.7) × 10(-4)—that is, approximately three times the terrestrial value. Previous cometary measurements and our new finding suggest a wide range of D/H ratios in the water within Jupiter family objects and preclude the idea that this reservoir is solely composed of Earth ocean-like water.

During Cassini's initial orbit, we observed a dynamic magnetosphere composed primarily of a complex mixture of water-derived atomic and molecular ions. We have identified four distinct regions characterized by differences in both bulk plasma properties and ion composition. Protons are the dominant species outside about 9 RS (where RS is the radial distance from the center of Saturn), whereas inside, the plasma consists primarily of a corotating comet-like mix of water-derived ions with approximately 3% N+. Over the A and B rings, we found an ionosphere in which O2+ and O+ are dominant, which suggests the possible existence of a layer of O2 gas similar to the atmospheres of Europa and Ganymede.

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Abstract:Comets contain the best-preserved material from the beginning of our planetary system. Their nuclei and comae composition reveal clues about physical and chemical conditions during the early Solar system when comets formed. ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) onboard the Rosetta spacecraft has measured the coma composition of comet 67P/Churyumov-Gerasimenko with well sampled time resolution per rotation. Measurements were made over many comet rotation periods and a wide range of latitudes. These measurements show large fluctuations in composition in a heterogeneous coma that has diurnal and possibly seasonal variations in the major outgassing species: H 2 O, CO, and CO 2 . These results indicate a complex coma-nucleus relationship where seasonal variations may be driven by temperature differences just below the comet surface.One Sentence Summary: ROSINA/DFMS shows that 67P/Churyumov-Gerasimenko has a highly heterogeneous coma with large diurnal and possibly seasonal variations. Main Text:Initially, comets were classified depending on the location where they formed in the protoplanetary disc (1,2). This classification assumed a similar composition of the nucleus within a given formation region. No cometary nucleus composition has been sampled in situ. Rather, it is implicitly assumed that measurements of the outgassing of comets reveal the composition of the volatile components of the nucleus. However, compositional homogeneity of at least one comet was confirmed by studying outgassing from the fragments of the broken up comet Schwassmann-Wachmann 3 (3). Detailed observations of other cometary comae indicated that there is evidence of heterogeneity. Missions to comet Halley detected release of volatiles in multiple jet-like features that were dominantly seen on the sunlit side of the nucleus (4, 5). The Deep Impact mission detected asymmetries in composition in the coma of Tempel 1 (6). In particular, these remote sensing observations at Tempel 1 indicated an absence of correlation between H 2 O and CO 2 in the coma.Detailed, close up cometary images have also showed visible differences between different areas of cometary nuclei. These images suggested that heterogeneity in the coma of a comet may be related to heterogeneity of the nucleus. Observations by EPOXI at Hartley 2 in 2010 near perihelion indicated that the nucleus is complex, with two different sized lobes separated by a middle waist region that is smoother and lighter in color (7). Outgassing from sunlit surfaces of the nucleus revealed that the waist and one of the lobes were very active. A CO 2 source was detected at the small lobe of the comet, while the waist was more active in H 2 O and had a significantly lower CO 2 content. Based on these coma observations, it has been tentatively suggested that the heterogeneity in the comet's nucleus was primordial (7). Seasonal effects could not be ruled out because the observations also showed a complex rotational state for the comet (7). The smaller of the two lobes ...

Comets are considered to be some of the most pristine and unprocessed solar system objects accessible to in-situ exploration. Investigating their molecular and elemental composition takes us on a journey back to the early period of our solar system and possibly even further. In this work, we deduce the bulk abundances of the major volatile species in comet 67P/Churyumov-Gerasimenko, the target of the European Space Agency's Rosetta mission. The basis are measurements obtained with the ROSINA instrument suite on board the Rosetta orbiter during a suitable period of high outgassing near perihelion. The results are combined with both gas and dust composition measurements published in the literature. This provides an integrated inventory of the major elements present in the nucleus of 67P/Churyumov-Gerasimenko. Similar to comet 1P/Halley, which was visited by ESA's Giotto spacecraft in 1986, comet 67P/Churyumov-Gerasimenko also shows near-solar abundances of oxygen and carbon, whereas hydrogen and nitrogen are depleted compared to solar. Still, the degree of devolatilization is lower than that of inner solar system objects, * E-mail: martin.rubin@space.unibe.ch 2 including meteorites and the Earth. This supports the idea that comets are among the most pristine objects in our solar system.

Abstract. We examine the circulation of heavy ions of planetary origin within Mercury's magnetosphere. Using single particle trajectory calculations, we focus on the dynamics of sodium ions, one of the main species that are ejected from the planet's surface. The numerical simulations reveal a significant population in the near-Mercury environment in the nightside sector, with energetic (several keV) Na + densities that reach several tenths cm −3 at planetary perihelion. At aphelion, a lesser (by about one order of magnitude) density contribution is obtained, due to weaker photon flux and solar wind flux. The numerical simulations also display several features of interest that follow from the small spatial scales of Mercury's magnetosphere. First, in contrast to the situation prevailing at Earth, ions in the magnetospheric lobes are found to be relatively energetic (a few hundreds of eV), despite the low-energy character of the exospheric source. This results from enhanced centrifugal acceleration during E × B transport over the polar cap. Second, the large Larmor radii in the mid-tail result in the loss of most Na + into the dusk flank at radial distances greater than a few planetary radii. Because gyroradii are comparable to, or larger than, the magnetic field variation length scale, the Na + motion is also found to be non-adiabatic throughout most of Mercury's equatorial magnetosphere, leading to chaotic scattering into the loss cone or meandering (Speiser-type) motion in the near-tail. As a direct consequence, a localized region of energetic Na + precipitation develops at the planet's surface. In this region which extends over a wide range of longitudes at mid-latitudes (∼30 • -40 • ), one may expect additional sputtering of planetary material.