The northeastern Baffin Bay continental margin, which experiences high sediment accumulation rates, is an excellent location to study Holocene sedimentary variations. However, it is often difficult to obtain reliable chronologies of the sediment archives using traditional methods (δ18O and radiocarbon) due to specific oceanographic conditions (e.g. corrosive bottom waters). Here we propose a chronostratigraphy of three cores collected on the northwestern Greenland margin (AMD14‐204, AMD14‐210 and AMD14‐Kane2B) based on a combination of radiocarbon dating and palaeomagnetic records. Geophysical properties of discrete samples were used to verify the reliability of the palaeomagnetic records. Palaeomagnetic analyses indicate a strong and stable natural remanent magnetization carried by low coercivity ferrimagnetic minerals (magnetite) in the pseudo‐single domain grain size range. Correlation of the full palaeomagnetic vector (inclination, declination, and relative palaeointensity) was used to establish a reliable chronostratigraphical framework for two of the cores (AMD14‐204 and AMD14‐210) and to propose an original palaeomagnetic record for the previously 14C‐dated core AMD14‐Kane2B that covers most of the Holocene. Overall, this new chronostratigraphy allowed improvement of the timing of the main palaeoenvironmental changes that occurred in this area during the Holocene.
Mineralogical, geochemical, magnetic, and siliciclastic grain‐size signatures of 34 surface sediment samples from the Mackenzie‐Beaufort Sea Slope and Amundsen Gulf were studied in order to better constrain the redox status, detrital particle provenance, and sediment dynamics in the western Canadian Arctic. Redox‐sensitive elements (Mn, Fe, V, Cr, Zn) indicate that modern sedimentary deposition within the Mackenzie‐Beaufort Sea Slope and Amundsen Gulf took place under oxic bottom‐water conditions, with more turbulent mixing conditions and thus a well‐oxygenated water column prevailing within the Amundsen Gulf. The analytical data obtained, combined with multivariate statistical (notably, principal component and fuzzy c‐means clustering analyses) and spatial analyses, allowed the division of the study area into four provinces with distinct sedimentary compositions: (1) the Mackenzie Trough‐Canadian Beaufort Shelf with high phyllosilicate‐Fe oxide‐magnetite and Al‐K‐Ti‐Fe‐Cr‐V‐Zn‐P contents; (2) Southwestern Banks Island, characterized by high dolomite‐K‐feldspar and Ca‐Mg‐LOI contents; (3) the Central Amundsen Gulf, a transitional zone typified by intermediate phyllosilicate‐magnetite‐K‐feldspar‐dolomite and Al‐K‐Ti‐Fe‐Mn‐V‐Zn‐Sr‐Ca‐Mg‐LOI contents; and (4) mud volcanoes on the Canadian Beaufort Shelf distinguished by poorly sorted coarse‐silt with high quartz‐plagioclase‐authigenic carbonate and Si‐Zr contents, as well as high magnetic susceptibility. Our results also confirm that the present‐day sedimentary dynamics on the Canadian Beaufort Shelf is mainly controlled by sediment supply from the Mackenzie River. Overall, these insights provide a basis for future studies using mineralogical, geochemical, and magnetic signatures of Canadian Arctic sediments in order to reconstruct past variations in sediment inputs and transport pathways related to late Quaternary climate and oceanographic changes.
[1] Nd isotopic compositions ("Nd) of seawater profiles and deep-sea corals collected off the coast of Iberia and from the Bay of Biscay were measured (1) to constrain the Nd isotopic composition of water masses along the southwest European margin, (2) to track the Mediterranean Outflow Water (MOW) during its northward propagation, and (3) to establish hydrological changes during the last 1500 years. The Eastern North Atlantic Central Water (ENACW) is characterized by Nd isotopic composition of around −12.0. Mediterranean Sea Water (MSW) is collected from 800 and 1200 m depth and is characterized by "Nd values ranging from −10.9, off the coast of Iberia, to −11.6 in the Bay of Biscay. These "Nd results suggest a strong dilution of the pure MOW at the Strait of Gibraltar ("Nd −9.4) of approximately 40%Copyright 2011 by the American Geophysical Union 1 of 14 and 30% along its northward circulation pathway essentially with a contribution from ENACW. At around 2000 m depth, "Nd water profiles display the occurrence of a nonradiogenic water mass ("Nd −13), originating from the Labrador Sea (Labrador Sea Water). Fossil deep-sea corals, dated between 84 and 1500 years, display Nd isotopic compositions that vary moderately from present-day seawater values, suggesting a weaker influence of MOW in the formation of MSW during the Dark Ages and the Little Ice Age. These recent cold events seem to be associated with a reduction in the northward penetration of MSW, which may result from a greater eastward extension of the middepth subpolar gyre and/or a reduction of MSW formation, likely tied to a variation in deep Mediterranean water production.
Cored sediments from the Pigmy Basin, northern Gulf of Mexico, were analyzed in order to better constrain late deglacial and early Holocene paleoenvironmental and sedimentary changes in response to North American climate evolution. Mineralogical and geochemical proxies indicate the succession of two sedimentary regimes: dominantly detrital during the deglaciation (15-12.9 cal ka BP) whereas biogenic contribution relatively increased later on during the Younger Dryas and early Holocene (12.9 and 10 cal ka BP). Geochemical data reveal that the deglacial record mainly reflects variations of terrigenous supply via the Mississippi River rather than modifications of redox conditions in the basin. Specific variations of almost all the parameters measured in this paper are synchronous with the main deglacial meltwater episode (Meltwater Spike) described or modeled in previous marine or continental studies. During this episode, most parameters display ''stair-step-like'' -pattern variations highlighting three successive steps within the main meltwater flow. Variations in grain-size and clay mineral assemblage recorded in the Pigmy Basin indicate that the erosional regime was very strong on land during the first part of the Meltwater Spike, and then milder, inducing more subtle modifications in the sedimentary regime in this part of the Gulf. Specific geochemical and mineralogical signatures (notably, clay minerals and trace metal geochemistry) pinpoint a dominant origin from NW North America for detrital particles reflecting meltwater outflow from the south-western Laurentide Ice Sheet (LIS) margin 2 during the most intense freshwater discharge. The observed decrease of the sedimentation rate from about 200 to 25 cm/ka at ca 12.9 ka evidenced a drastic decrease of erosional processes during late phase of discharge, consistently with the hypotheses of major reduction of meltwater flow. The major modification at 12.9 cal ka BP is interpreted to result from both modifications of the main Mississippi fluvial regime due to eastward and northward rerouting of meltwater flow at the onset of the Younger Dryas, and the increase of sea-surface temperature linked to insolation. Finally, slight grain-size modifications suggest that some freshwater discharges may have episodically reached the Gulf of Mexico after the Younger Dryas reflecting possible small adjustments of the postglacial hydrological regime.
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