Utilization of coal in the current energy sector requires implementation of highly-efficient technologies to meet the dual targets of increased energy-efficiency and reduced carbon footprint. Efforts are being made to develop gasification systems with lower unit emissions of carbon dioxide and other contaminants, capable of handling various feedstocks and flexible in terms of products generated (synthesis gas, hydrogen, heat and electricity). The utilization of captured carbon dioxide and waste heat in industrial processes are considered to further contribute to the advancements in energy-efficient and low-emission technological solutions. This paper presents the experimental results on the incorporation of carbon dioxide into the valorization cycle as a reactant in coal gasification. Tests were performed on a laboratory scale moving bed gasifier using three system configurations with various simulated waste heat utilization scenarios. The temperature range covered 700, 800 and 900 °C and the gasification agents used were carbon dioxide, oxygen and the mixture of 30 vol.% carbon dioxide in oxygen. The combined effect of the process parameters applied on the efficiency of coal processing in terms of the gas yields, composition and calorific value was studied and the experimental data were explored using Principal Component Analysis.

No abstract

No abstract

The problem of reducing carbon dioxide emissions from flue gas, particularly from flue gas originating from coal-firing CFB systems, is currently an important challenge. Many centers around the world have tested post-combustion CO2 capture systems. One of these systems, operated using DR-VPSA adsorption technology (dual-reflux vacuum pressure swing adsorption), was tested under the Strategic Project in Poland. The flue gas in this study originated from a supercritical CFB boiler (460 MWe). An important problem involved in capturing CO2 from flue gas is the occurrence of SO2 and NOx. These substances have a negative effect on the CO2 adsorption process. In this study, commercial impregnated activated carbon was used to remove SO2 and NOx from CFB flue gas in the pre-treatment section during the tests of a pilot CO2 capture unit in a large-scale CFB boiler at the Lagisza Power Plant (Poland). The spent activated carbon was analyzed using several different methods (N2 adsorption–desorption isotherms, SEM-EDX, XRD, FTIR, and TG) to evaluate the efficiency of the operation and life span of the adsorbent used in the SO2 and NOx removal unit. The results demonstrate that using commercial impregnated activated carbon in the pre-treatment section ensures sufficient flue gas purification and the removal of sulfur oxides but remains insufficient for nitrogen oxides.

The near and mid-term future of the existing Polish coal-fired power fleet is uncertain. The longer-term operation of unabated coal power is incompatible with climate policy and is economically challenging because of the increasing price of CO2 emission allowances in the EU. The results of the techno-economic analysis presented in this paper indicate that the retrofit of existing coal-fired units, by means of replacing coal-fired boilers with small modular reactors, may be an interesting option for the Polish energy sector. It has been shown that the retrofit can reduce the costs in relation to greenfield investments by as much as 35%. This analysis focuses on the repowering of a 460 MW supercritical coal-fired unit based on the Łagisza power plant design with high temperature small modular nuclear reactors based on the 320 MWth unit design by Kairos Power. The technical analyses did not show any major difficulties in integrating. The economic analyses show that the proposed retrofits can be economically justified, and, in this respect, they are more advantageous than greenfield investments. For the base economic scenario, the difference in NPV (Net Present Value) is more favorable for the retrofit by 556.9 M€ and the discounted payback period for this pathway is 10 years.

No abstract

No abstract

The utilization of carbon dioxide and combustion products in cost- and energy-efficient technologies is an important element of creating sustainable energy systems, particularly in the transition period towards carbon neutrality and in light of the latest political developments, when solid fuels are still competing for a dominant role in securing energy supplies. Within the study presented, bituminous coal-derived fluidized bed fly ash samples of high calcium content, treated using a dry carbonation method under ambient conditions, were tested in terms of their specific properties to determine their usability in the preparation of injection mixtures for the filling of voids after shallow mining activities and other selected geo-engineering techniques. The study goes beyond the existing literature in terms of the carbonation method used, alkaline earth metal source, scale of the experiment, process conditions employed and product application studied. The results showed that the bituminous coal-derived fluidized bed fly ash, carbonated using the direct method adopted, may be successfully employed as the main solid component (over 82% w/w) of the injection mixtures for filling voids after shallow mining activities. The achievable compressive strength of a few MPa makes these materials applicable also in terms of ground strengthening in case it is required in light of the expected land development options to be employed. All principal materials used in the injection mixtures developed (carbonated fluidized bed fly ash, carbon dioxide, bottom ash) are industrial waste, and the carbonation method employed is simple and performed under ambient conditions, which reduces the required energy and cost input of filling mixture production, avoids the surface waste storage requirements, and contributes to the development of low energy-intensive carbon dioxide utilization and solid waste valorization methods.