Abstract. Accurate assessment of anthropogenic carbon dioxide (CO 2 ) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere -the "global carbon budget" -is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. CO 2 emissions from fossil fuels and industry (E FF ) are based on energy statistics and cement production data, respectively, while emissions from land-use change (E LUC ), mainly deforestation, are based on land-cover change data and bookkeeping models. The global atmospheric CO 2 concentration is measured directly and its rate of growth (G ATM ) is computed from the annual changes in concentration. The ocean CO 2 sink (S OCEAN ) and terrestrial CO 2 sink (S LAND ) are estimated with global process models constrained by observations. The resulting carbon budget imbalance (B IM ), the difference between the estimated total emissions and the estimated changes in the atmosphere, ocean, and terrestrial biosphere, is a measure of imperfect data and understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ . For the last decade available (2007)(2008)(2009)(2010)(2011)(2012)(2013)(2014)(2015)(2016), E FF was 9.4 ± 0.5 GtC yr −1 , E LUC 1.3 ± 0.7 GtC yr −1 , G ATM 4.7 ± 0.1 GtC yr −1 , S OCEAN 2.4 ± 0.5 GtC yr −1 , and S LAND 3.0 ± 0.8 GtC yr −1 , with a budget imbalance B IM of 0.6 GtC yr −1 indicating overestimated emissions and/or underestimated sinks. For year 2016 alone, the growth in E FF was approximately zero and emissions remained at 9.9 ± 0.5 GtC yr −1 . Also for 2016, E LUC was 1.3 ± 0.7 GtC yr −1 , G ATM was 6.1 ± 0.2 GtC yr −1 , S OCEAN was 2.6 ± 0.5 GtC yr −1 , and S LAND was 2.7 ± 1.0 GtC yr −1 , with a small B IM of −0.3 GtC. G ATM continued to be higher in 2016 compared to the past decade (2007)(2008)(2009)(2010)(2011)(2012)(2013)(2014)(2015)(2016), reflecting in part the high fossil emissions and the small S LAND consistent with El Niño conditions. The global atmospheric CO 2 concentration reached 402.8 ± 0.1 ppm averaged over 2016. For 2017, preliminary data for the first 6-9 months indicate a renewed growth in E FF of +2.0 % (range of 0.8 to 3.0 %) based on national emissions projections for China, USA, and India, and projections of gross domestic product (GDP) corrected for recent changes in the carbon intensity of the economy for the rest of the world. This living data update documents changes in the methods and data sets used in this new global carbon budget compared with previous publications of this data set (Le Quéré et al

Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere – the "global carbon budget" – is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. CO2 emissions from fossil fuels and industry (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on land-cover change data and bookkeeping models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The ocean CO2 sink (SOCEAN) and terrestrial CO2 sink (SLAND) are estimated with global process models constrained by observations. The resulting carbon budget imbalance (BIM), the difference between the estimated total emissions and the estimated changes in the atmosphere, ocean, and terrestrial biosphere, is a measure of our imperfect data and understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the last decade available (2007–2016), EFF was 9.4 ± 0.5 GtC yr−1, ELUC 1.3 ± 0.7 GtC yr−1, GATM 4.7 ± 0.1 GtC yr−1, SOCEAN 2.4 ± 0.5 GtC yr−1, and SLAND 3.0 ± 0.8 GtC yr−1, with a budget imbalance BIM of 0.6 GtC yr−1 indicating overestimated emissions and/or underestimated sinks. For year 2016 alone, the growth in EFF was approximately zero and emissions remained at 9.9 ± 0.5 GtC yr−1. Also for 2016, ELUC was 1.3 ± 0.7 GtC yr−1, GATM was 6.1 ± 0.2 GtC yr−1, SOCEAN was 2.6 ± 0.5 GtC yr−1 and SLAND was 2.7 ± 1.0 GtC yr−1, with a small BIM of −0.3 GtC. GATM continued to be higher in 2016 compared to the past decade (2007–2016), reflecting in part the higher fossil emissions and smaller SLAND for that year consistent with El Niño conditions. The global atmospheric CO2 concentration reached 402.8 ± 0.1 ppm averaged over 2016. For 2017, preliminary data indicate a renewed growth in EFF of +2.0 % (range of 0.8 % to 3.0 %) based on national emissions projections for China, USA, and India, and projections of Gross Domestic Product corrected for recent changes in the carbon intensity of the economy for the rest of the world. For 2017, initial data indicate an increase in atmospheric CO2 concentration of around 5.3 GtC (2.5 ppm), attributed to a combination of increasing emissions and receding El Niño conditions. This living data update documents changes in the methods and data sets used in this new global carbon budget compared with previous publications of this data set

Syntheses of carbonate chemistry spatial patterns are important for predicting ocean acidification impacts, but are lacking in coastal oceans. Here, we show that along the North American Atlantic and Gulf coasts the meridional distributions of dissolved inorganic carbon (DIC) and carbonate mineral saturation state (Ω) are controlled by partial equilibrium with the atmosphere resulting in relatively low DIC and high Ω in warm southern waters and the opposite in cold northern waters. However, pH and the partial pressure of CO2 (pCO2) do not exhibit a simple spatial pattern and are controlled by local physical and net biological processes which impede equilibrium with the atmosphere. Along the Pacific coast, upwelling brings subsurface waters with low Ω and pH to the surface where net biological production works to raise their values. Different temperature sensitivities of carbonate properties and different timescales of influencing processes lead to contrasting property distributions within and among margins.

Coastal acidification in southeastern U.S. estuaries and coastal waters is influenced by biological activity, runoff from the land, and increasing carbon dioxide in the atmosphere. Acidification can negatively impact coastal resources such as shellfish, finfish, and coral reefs, and the communities that rely on them. Organismal responses for species located in the U.S. Southeast document large negative impacts of acidification, especially in larval stages. For example, the toxicity of pesticides increases under acidified conditions and the combination of acidification and low oxygen has profoundly negative influences on genes regulating oxygen consumption. In corals, the rate of calcification decreases with acidification and processes such as wound recovery, reproduction, and recruitment are negatively impacted. Minimizing the changes in global ocean chemistry will ultimately depend on the reduction of carbon dioxide emissions, but adaptation to these changes and mitigation of the local stressors that exacerbate global acidification can be addressed locally. The evolution of our knowledge of acidification, from basic understanding of the problem to the emergence of applied research and monitoring, has been facilitated by the development of regional Coastal Acidification Networks (CANs) across the United States. This synthesis is a product of the Southeast Coastal and Ocean Acidification Network (SOCAN). SOCAN was established to better understand acidification in the coastal waters of the U.S. Southeast and to foster communication among scientists, resource managers, businesses, and governments

Carbon dioxide partial pressure (pCO 2) in surface seawater was continuously recorded every three hours from 18 July 2006 through 31 October 2007 using a moored autonomous pCO 2 (MAPCO 2) system deployed on the Gray's Reef buoy off the coast of Georgia, USA. Surface water pCO 2 (average 373 ± 52 µatm) showed a clear seasonal pattern, undersaturated with respect to the atmosphere in cold months and generally oversaturated in warm months. High temporal resolution observations revealed important events not captured in previous ship-based observations, such as sporadically occurring biological CO 2 uptake during April-June 2007. In addition to a qualitative analysis of the primary drivers of pCO 2 variability based on property regressions, we quantified contributions of temperature, air-sea exchange, mixing, and biological processes to monthly pCO 2 variations using a 1-D mass budget model. Although temperature played a dominant role in the annual cycle of pCO 2 , river inputs especially in the wet season, biological respiration in peak summer, and biological production during April-June 2007 also substantially influenced seawater pCO 2. Furthermore, sea surface pCO 2 was higher in September-October 2007 than in September-October 2006, associated with increased river inputs in fall 2007. On an annual basis this site was a moderate atmospheric CO 2 sink, and was autotrophic as revealed by monthly mean net community production (NCP) in the mixed layer. If the sporadic short productive events during April-May 2007 were missed by the sampling schedule, one would conclude erroneously that the site is heterotrophic. While previous shipbased pCO 2 data collected around this buoy site agreed with the buoy CO 2 data on seasonal scales, high resolution buoy observations revealed that the cruise-based surveys undersampled temporal variability in coastal waters, which could greatly bias the estimates of air-sea CO 2 fluxes or annual NCP, and even produce contradictory results.