This paper deals with the possibility of partial replacement of blast furnace slag with fly ash and fly ash after denitrification by SNCR method in alkali-activated materials based on granulated blast furnace slag. The aim of this paper is to verify the effect of fly ash on properties of alkali-activated materials based on blast furnace granulated slag. Frost resistance and resistance to aggressive environments, represented by demineralized water were tested. The reference mixture was based on blast furnace granulated slag activated by sodium water glass with silicate modulus of 2. Mixtures with an ash content of 10, 20, and 30% were then compared with the reference mixture. The influence of the denitrification process on fly ash and its use in mixed alkali activated materials was also compared. As a part of the experiment, alkali-activated pastes were also prepared. Infrared spectroscopy with Furier transformation was subsequently determined on these pastes. The reference mixture achieved the highest compressive strength in the experiment and the strength decreased with increasing amount of fly ash. In terms of flexural strength, the highest values were reached for mixtures with 10% slag replacement by fly ash. In the case of frost resistance, the significant increase of flexural strength, which was 50% for the reference mixture, is particularly interesting. For compressive strength, the frost resistance coefficient ranged from 0.95 to 1.00. In the case of resistance to aggressive environments, no differences were observed in the compressive strength, on the other hand, flexural strength decrease of up to 20% was detected for 10 and 20 percent replacement of slag with fly ash that did not undergo denitrification. Monitored properties did not show any negative effect of the denitrification process on fly ash properties. Infrared spectroscopy identified the main hydration product in the region of 945 cm-1which is a C-(A)-S-H gel and in combined mixtures with fly ash also N-A-S-H gel. Doi: 10.28991/esj-2020-01247 Full Text: PDF
Alkali-activated materials are formed by the alkaline activation of inorganic materials and are characterized by the wide range of potential use. The objective of experiment was to investigate the possibility of use fine-grained alkali activated composites in the construction industry. Selected properties of alkali-activated systems based on granulated blast furnace slag and fine-grained aggregates were determined. At the beginning of the experiment, different samples prepared of 3 types of activators were tested, basic properties (time of workability, initial and final setting time, compressive and flexural strength) and also a possibility of selected retarder use was determined. Then, samples with the best potencial to presumed use were tested in detail and a possibility use as a substitute for selected construction materials were evaluated. On the basis of determined properties, prepared composites could be used as reprofiling mortars, materials for cracks repairing or socle plasters.
Alkali-activated materials are alternative building binders, where secondary raw materials are processed. The possibility of using landfilled waste materials in the building industry increases their potential application in construction practice, and they are therefore subject to extensive research, especially in recent years. This paper briefly summarizes the interesting results of an experiment aimed at verifying the possibility of applying cement by-pass dust (CBPD) in the preparation of alkali-activated materials. The research was focused on the possibilities of using these wastes for the preparation of small elements of garden architecture. This work also briefly summarized the interesting results of an experiment aimed at verifying the possibility of applying cement by-pass dust (CBPD) in the preparation of alkali-activated materials. In the experiment, a mixture of blast furnace granulated slag, fly ash and cement by-pass dust was alkali activated with sodium metasilicate.
The paper deals with the possibility of using fly ash, including fly ash after denitrification by SNCR method, from the Třebovice power plant as an admixture to mixtures based on alkali-activated blast furnace slag in order to improve selected physical, mechanical and durability properties.
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