This article discusses the possibilities of using radiation cross-linked high density polyethylene (HDPEx) acting as a filler in the original high density polyethylene (HDPE) matrix. The newly created composite is one of the possible answers to questions relating to the processing of radiation cross-linked thermoplastics. Radiation cross-linked networking is—nowadays, a commonly used technology that can significantly modify the properties of many types of thermoplastics. This paper describes the influence of the concentration of filler, in the form of grit or powder obtained by the grinding/milling of products/industrial waste from radiation cross-linked high density polyethylene (rHDPEx) on the mechanical and processing properties and the composite structure. It was determined that, by varying the concentration of the filler, it is possible to influence the mechanical behaviour of the composite. The mechanical properties of the new composite—measured at room temperature, are generally comparable or better than the same properties of the original thermoplastic. This creates very good assumptions for the effective and economically acceptable, processing of high density polyethylene (rHDPEx) waste. Its processability however, is limited; it can be processed by injection moulding up to 60 wt %.
Radiation processing of polymers is a well-established and economical commercial method of precisely modifying the properties of polymers. The principle of radiation processing is the ability of high energy radiation to produce reactive cations, anions and free radicals in materials. The industrial applications of the radiation processing of plastics and composites include polymerization, cross-linking, degradation and grafting. Radiation processing mainly involves the use of either electron beams from electron accelerators or gamma radiation from Cobalt-60 sources. The PBT Polybutylene terephthalate tested showed significant changes of temperature stability and mechanical properties after irradiation. From this point view, new applications could also be seen in areas with service temperatures higher than their former melting point. The comparison of the temperature stability and mechanical properties of irradiated and non-irradiated PBT is presented in this paper.
This article deals with the study of the utilisation of irradiated HDPE products after their end-of-life cycle. Today, polymer waste processing is a matter of evermore intensive discussion. Common thermoplastic waste recycling-especially in the case of wastes with a defined composition-is generally well-known-and frequently used. On the contrary, processing cross-linked plastics is impossible to do in the same way as with virgin thermoplastics-mainly due to the impossibility of remelting them. The possibility of using waste in the form of grit or a powder, made from cross-linked High Density PolyEthylene (rHDPEx) products, after their end-of-life cycle, as a filler for virgin Low Density PolyEthylene (LDPE) was tested in a matrix. It was found that both the mechanical behaviour and processability of new composites with an LDPE matrix, with rHDPEx as a filler, depend-to a high degree-on the amount of the filler. The composite can be processed up to 60% of the filler content. The Polymer Mixture Fluidity dropped significantly, in line with the amount of filler, while the mechanical properties, on the other hand, predominantly grew with the increasing amount of rHDPEx.
This work presents a Free Form Deformation (FFD) method for shape parameterization and applications on aerodynamic aircraft design. Our objective is to accurately resolve problems of shape optimization including geometric constraints. Here we couple an FFD based on NURBS with a Radial Basis Function (RBF) in order to improve the control of the deformations and enable a more accurate resolution of constraints even when using a coarse lattice. Our investigations also focus on efficiency, showing for instance that the highest NURBS degree improve the resolution of the optimization problem when the solution is a smooth shape in 2D without influencing the cost of optimization. This indicates a mean to avoid wiggles in shapes deformed by FFD without deteriorating the condition of the problem. Other applications in 2D and 3D also illustrate the behaviour of the FFD parameterization when refining or adapting the position of the lattice vertices.
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