. The control of magnetic anisotropy is a key issue in the development of molecule-metal interfaces for magnetic applications, both at the single-molecule 12 and extended-film level 13 . In metallic multilayers used as storage media or spin-valve devices at present, tuning of the magnetic anisotropy is achieved either by a careful choice of the overlayer/substrate composition and thickness or by oxidation of the magnetic elements 11,14,15 . Recent studies showed that the magnetization direction of surface-supported paramagnetic molecules can be controlled through exchange coupling with a magnetic film, which provides robust ferromagnetic properties but does not enable each molecule to be switched independently from the substrate or its neighbours 16,17 . Alternatively, theoretical work suggested that the sign of magnetic anisotropy could be reversed in metal-organic complexes by exploiting oxidation processes that affect the hybridization of molecular orbitals with metal states carrying non-zero orbital magnetization 18 . Here, we investigate supramolecular self-assembly on a non-magnetic Cu surface as a means to produce two-dimensional

The robustness of the gapless topological surface state hosted by a 3D topological insulator against perturbations of magnetic origin has been the focus of recent investigations. We present a comprehensive study of the magnetic properties of Fe impurities on a prototypical 3D topological insulator Bi2Se3 using local low temperature scanning tunneling microscopy and integral x-ray magnetic circular dichroism techniques. Single Fe adatoms on the Bi2Se3 surface, in the coverage range ≈ 1% are heavily relaxed into the surface and exhibit a magnetic easy axis within the surface-plane, contrary to what was assumed in recent investigations on the opening of a gap. Using ab initio approaches, we demonstrate that an in-plane easy axis arises from the combination of the crystal field and dynamic hybridization effects.Topological insulators (TI) have demanded heavy interest from the scientific community as a new class of materials illuminating fascinating yet exotic physics and offering large potential for applications in the field of spintronics [1]. TI host a gapless topological surface state (TSS) which exhibits a Dirac-cone like dispersion. However, unlike in the case of graphene, the Dirac cone is located in the center of the Brillouin-zone and the spin and momentum degrees of freedom are locked. The latter so-called topological quality of the TSS is protected by time-reversal symmetry which leads to a variety of interesting effects. For example, these materials may be a forum for Majorana fermions [2], a topological magnetoelectric effect [3], and a quantized anomalous Hall effect [4].The locking of both spin and momentum degrees of freedom leads to the suppression of 180 • elastic backscattering of TSS electrons in the absence of spin-flip processes. The robustness of these "topologically protected" processes, when introducing impurities which break time reversal symmetry, is of critical importance for spinbased transport in such materials. It has been suggested that the interaction between magnetic impurities and the topological state can cause an opening of an energy gap at the Dirac point (DP), provided that the magnetic order is oriented normal to the surface plane [5][6][7]. Nevertheless, the stability of the TSS against local magnetic perturbations is currently under heavy debate [8][9][10], since little is known about the fundamental interface effects of magnetic entities with TI surfaces as well as the static magnetic properties of impurities in these materials.In this work we present a comprehensive study of the magnetic properties of iron impurities on a prototypical TI Bi 2 Se 3 using local scanning tunneling microscopy (STM) and integral x-ray magnetic circular dichroism (XMCD) techniques. We show that the multiplet structure visible in x-ray absorption spectra reflect a high-spin state of the adsorbed Fe impurities, which are confirmed to bind at hollow sites of the surface lattice, under the influence of trigonal crystal fields given in hollow site positions of the Bi 2 Se 3 surface. In contrary to rec...

The magnetic properties of isolated TbPc(2) molecules supported on a Cu(100) surface are investigated by X-ray magnetic circular dichroism at 8 K in magnetic fields up to 5 T. The crystal field and magnetic properties of single molecules are found to be robust upon adsorption on a metal substrate. The Tb magnetic moment has Ising-like magnetization; XMCD spectra combined with multiplet calculations show that the saturation orbital and spin magnetic moment values reach 3 and 6 mu(B), respectively.