In second‐ to fifth‐order streams that drain old‐growth timber in western Washington, characteristics and function of woody debris changed in relation to stream size. Average diameter, length, and volume of pieces of wood increased as stream size increased, whereas the frequency of occurrence of woody debris decreased. In streams with channel widths less than 7 m, 40% of the pieces of debris were oriented perpendicularly to the axis of flow; in streams with channel widths over 7 m, more than 40% of the pieces were oriented downstream. The types of pools most commonly associated with pieces of wood changed from plunge pools in small streams (42%) to debris scour pools in larger systems (62%). Pool area was correlated with the volume of the piece of wood forming the pool in streams of all sizes. However, this relationship was most evident in larger channels. Nearly 40% of the pieces of wood in channels less than 7 m wide were associated with sediment accumulations. Less than 30% of the pieces retained sediment in channels from 7 to 10 m wide, and less than 20% retained sediment in channels greater than 10 m wide. Surface area of sediment accumulations and the volume of the piece of wood forming the accumulation were related in all streams, but the relationship was clearest in the larger channels. Accumulations of particulate organic matter associated with woody debris were more frequent in small streams but were larger in large streams. No relationship was observed between the volume of fine particulate organic matter accumulated by a piece of wood and the piece of woodˈs volume.

Amount of large woody debris (LWD) surveyed in 70 stream reaches flowing through old-growth, clear-cut, and second-growth forests decreased with increasing stream size for all stand types but was greatest at old-growth sites. Average piece volume was larger at old-growth sites than at other stand types in streams >10 m wide, but no differences were seen in smaller streams. Scour pools accounted for 90% of the wood-associated pools at second-growth and clear-cut sites but only 50% at old-growth sites, which contained more pools than other stand types, particularly for larger streams. Pool size was similar for all stand types in smaller streams, but averaged 10 m2 in streams >10 m wide at old-growth sites and 4 m2 for other stand types. Pool size was similar for all stand types in smaller streams. Sediment and fine organic matter retained by woody debris decreased with increasing stream size for ail stand types, but old-growth sites contained greater amounts of both materials than other stand types. The frequency of pool formation, the type of pool formed, and sediment accumulation were influenced by the amount of fine debris associated with LWD. Changes in LWD amount, characteristics, and function occurred very rapidly following removal of streamside vegetation.

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Logs of standard dimensions from five species of trees were submerged in a stream to evaluate changes in strength and decomposition over a period of 5 years. Changes in structural properties occurred only for wood near the outer surface of the logs. Nearly all bark was removed from the logs within 12 months. Diameter loss for the five species ranged from 10.6 mm (western hemlock Tsuga heterophylla) to 21.8 mm (bigleaf maple Acer macrophyllum) after 5 years. Decreases in the density of surface wood for the five species ranged from 23% (red alder Alnus rubra) to 31% (western hemlock). Modulus of rupture, modulus of elasticity, and wood density did not change for wood more than 12 mm from the log surface for any of the species. Bigleaf maple exhibited the highest resistance to rupture, and western redcedar Thuja plicata exhibited the lowest. Western redcedar was also the most easily flexed. Microbial activity on the surface of the logs was highest at the start of the experiment and decreased rapidly with time of immersion. The two hardwood species (bigleaf maple and red alder) generally had higher levels of microbial activity than the conifer species (Douglas fir Pseudotsuga menzesii, western hemlock, western redcedar) from 12 months through 60 months of immersion. Differences in the rate of decomposition between conifer and hardwood logs were much less than in terrestrial environments. Our results suggest that hardwood logs can be used in stream enhancement projects where the wood will be submerged.

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Since the majority of road drainage points in western Washington and Oregon enter small, often ephemeral streams rather than large, fish‐bearing waters, impact of road‐surface sediment on biota in permanent streams depends, to a large extent, on transport through these small watercourses. A series of experimental additions of road‐surface sediment was made to two ephemeral streams to examine the downstream transport of this material as a function of discharge and channel characteristics. These small streams were found to store large amounts of sediment washed from road surface. In no instance did either stream transport more than 45 percent of the added material to their mouths, distances of 95 and 125 m. Larger‐sized sediment particles were delivered at a lower rate than finer material. Added sediment <0.063 mm in size was transported efficiently through the systems at all but the lowest flows tested. Material between 0.5 and 0.063 mm and from 2.0 to 0.5 mm in size were retained at progressively higher rates, with sediment in the coarser size category never exceeding a delivery of 10 percent of the added material. There were significant differences in the transport of sediment in the two larger size categories between the two streams. These differences were due to a much greater amount of woody debris in the stream with the lower delivery rates, which acted to trap and hold sediment, as well as a slightly longer and less steep channel.

36mined in a like manner with A = 4 mm and B = 4 mm. Other diffractometer parameters and the method of estimation of standard deviations have been described previously.10 As a check on the stability of the instrument and the crystal, two reflections, the (200) and (002), were measured after every 30 reflections; no significant variation was noted.One independent quadrant of data was measured out to 28 = 1 10"; a total of 349 unique reflections ( I > 2 4 ) ) was obtained.The intensities were corrected for Lorentz and polarization effects but not for absorption, since the extreme values of the transmission factors were 0.90 and 0.95. The full-matrix. least-squares refinement was carried out using the Busing and Levy program O R F L S .~~ The function w(lF,l -I F c ( ) l 3 was minimized. No corrections were made for extinction or anomalous dispersion. Neutral atom scattering factors were taken from the compilations of Cromer and Waberl4 for C and N: those for hydrogen were from "International Tables for X-ray Crystallography." Final bond distances. angles, and errors were computed with the aid of the Busing, Martin, and Levy ORFFE program.16 Crystal structure illustrations were obtained with the program ORTEP.~' Fourier calculations were made with the A L F F~~ program. ~ ~~ Abstract:The formation and characterization of the first x complexes observed between ozone and aromatic or olefinic x systems are described. A correlation was made between the ionization potentials of a group of aromatic substrates and the wavelength of the absorption of their ozone complexes in the visible region. Two of the complexes were allowed to react with certain cis and trans olefins. The cis-trans ratios of the ozonides produced were different from those of the ozonides obtained by ozone alone in the cases of the cis-and rrans-l,2-diisopropylethylenes. However, there was no appreciable difference in the results obtained using complexed or uncomplexed ozone with the less bulky cis-and trans-3-hexenes.

We monitored habitat use and summer production of stocked underyearling coho salmon Oncorhynchus kisutch from 1983 to 1986 in three streams affected by the 1980 eruption of Mount St. Helens, Washington. Two streams were in the blast area and one was on a volcanic mud flow terrace. Midsummer water temperatures frequently exceeded presumed stressful thresholds and occasionally surpassed the incipient lethal limit. Temperatures at the study sites (up to 29.5°C) may have been the highest ever recorded in small streams in western Washington. In addition, there was relatively little submerged cover and limited pool habitat. Despite the severe conditions created by the eruption, production rates of stocked coho salmon at all sites ranged from 15.1 to 143.8 mg/m 2 -d (2.3-21.6 g/m 2 over an average 150-d summer period) and were equal to or greater than those measured in other streams of comparable size in the region. Coho salmon production in the streams was more strongly influenced by population biomass and density than by average individual growth rate. Production was also influenced by timing and average weight at stocking; larger fish stocked later in the summer had higher survival than smaller fish stocked earlier. Apparent summer mortality (true mortality plus emigration) may have been influenced by the presence of other salmonids. Coho salmon density at the end of summer was consistently lowest in the mud flow stream, the only site to have a large population of steelhead (anadromous rainbow trout Oncorhynchus my kiss, formerly Salmo gairdneri). We suspected that an abundance of both terrestrial and aquatic food was partly responsible for the high summer production of stocked coho salmon in what was an otherwise hostile environment.