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We report the characteristics of polymer∕nanocrystalline solar cells fabricated using an environmentally friendly water-soluble polythiophene and TiO2 in a bilayer configuration. The cells were made by dropping the polymer onto a TiO2 nanocrystalline film and then repeatedly sweeping a clean glass rod across the polymer as it dried. The devices showed an open circuit voltage of 0.81 V, a short circuit current density of 0.35mA∕cm2, a fill factor of 0.4, and an energy conversion efficiency of 0.13%. The water-soluble polythiophene showed significant photovoltaic behavior and the potential for use in solar cells.

Ultrashort-pulsed lasers have been demonstrated as effective tools for the nondestructive examination ͑NDE͒ of energy transport properties in thin films. After the instantaneous heating of the surface of a 100 nm metal film, it will take ϳ100 ps for the influence of the substrate to affect the surface temperature profile. Therefore, direct measurement of energy transport in a thin film sample requires a technique with picosecond temporal resolution. The pump-probe experimental technique is able to monitor the change in reflectance or transmittance of the sample surface as a function of time on a subpicosecond time scale. Changes in reflectance and transmittance can then be used to determine properties of the film. In the case of metals, the change in reflectance is related to changes in temperature and strain. The transient temperature profile at the surface is then used to determine the rate of coupling between the electron and phonon systems as well as the thermal conductivity of the material. In the case of semiconductors, the change in reflectance and transmittance is related to changes in the local electronic states and temperature. Transient thermotransmission experiments have been used extensively to observe electron-hole recombination phenomena and thermalization of hot electrons. Application of the transient thermoreflectance ͑TTR͒ and transient thermotransmittance ͑TTT͒ technique to the study of picosecond phenomena in metals and semiconductors will be discussed. The pump-probe experimental setup will be described, along with the details of the experimental apparatus in use at the University of Virginia. The thermal model applicable to ultrashort-pulsed laser heating of metals will be presented along with a discussion of the limitations of this model. Details of the data acquisition and interpretation of the experimental results will be given, including a discussion of the reflectance models used to relate the measured changes in reflectance to calculated changes in temperature. Finally, experimental results will be presented that demonstrate the use of the TTR technique for measuring the electron-phonon coupling factor and the thermal conductivity of thin metallic films. The use of the TTT technique to distinguish between different levels of doping and alloying in thin film samples of hydrogenated amorphous silicon will also be discussed briefly.

Increasing the size of nanoaerosols may be beneficial in a number of applications including filtration, particle size selection, and targeted respiratory drug delivery. A potential method to increase particle or droplet size is enhanced condensational growth (ECG), which involves combining the aerosol with saturated or supersaturated air. In this study, we characterize the ECG process in a model tubular geometry as a function of initial aerosol size (mean diameters – 150, 560 and 900 nm) and relative humidity conditions using both in vitro experiments and numerical modeling. Relative humidities (99.8 – 104%) and temperatures (25 – 39 °C) were evaluated that can safely be applied to either targeted respiratory drug delivery or personal aerosol filtration systems. For inlet saturated air temperatures above ambient conditions (30 and 39 °C), the initial nanoaerosols grew to a size range of 1000 – 3000 nm (1 – 3 μm) over a time period of 0.2 seconds. The numerical model results were generally consistent with the experimental findings and predicted final to initial diameter ratios of up to 8 after 0.2 s of humidity exposure and 14 at 1 s. Based on these observations, a respiratory drug delivery approach is suggested in which nanoaerosols in the size range of 500 nm are delivered in conjunction with a saturated or supersaturated air stream. The initial nanoaerosol size will ensure minimal deposition and loss in the mouth-throat region while condensational growth in the respiratory tract can be used to ensure maximal lung retention and to potentially target the site of deposition.