White etching cracking (WEC) is a subsurface bearing failure mechanism influenced by a number of factors, including lubricant composition. Certain metal-containing lubricants have been reported to promote WEC-induced failure; however, the exact mechanisms linking lubricant effects on WEC propensity are still not fully understood. An interesting field that has not been elucidated is the influence of additive concentration and tribofilm growth on WEC initiation, propagation, and failure. The investigations conducted in this work involved two series of oil formulations: one with additives that give rise to WEC (WEC oils) in different combinations and concentrations and another with additives that do not cause WEC (non-WEC oils). A mini traction machine (MTM) in combination with a spacer layer imaging machine (SLIM) was employed to study the growth of tribofilms and their influence on friction response. Insights from the MTM-SLIM study allowed for better interpretation of FE8 bearing tests. When using oils that contribute to WEC formation, the tribofilm-induced WEC mechanism was confirmed, with cracks initiating as early as after 20 h of FE8 testing. Metal-containing additives were found to favor the formation of WECs by generating a high-friction tribofilm and increasing the water content in the lubricant. Furthermore, the source of subsurface H associated with WEC failure is investigated using heavy water (D2O)-saturated oil. A mechanism of water dissociation induced in tribofilm growth (incubation period) is proposed in this article.

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Preparation of 39. A solution of p-bromo-JV,jV-dimethylaniline (1.00 g, 5.00 mmol) in 5 mL of dry THF was added to magnesium turnings (0.24 g, 10 mg-atom) under an argon atmosphere. A small crystal of iodine (~10 mg) was added, and the mixture was warmed at reflux for 2 h. Telluropyrone 1 (0.20 g, 0.56 mmol) in 5 mL of dry THF was added dropwise. The mixture was stirred at reflux for an hour more. The THF solution

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