New rotational line strengths for the C 2 Swan system (d 3 Π g -a 3 Π u ) have been calculated for vibrational bands with v ′ =0-10 and v ′′ =0-9, and J values up to J =34-96, based on previous observations in 30 vibrational bands. Line positions from several sources were combined with the results from recent deperturbation studies of the v ′ =4 and v ′ =6 states, and a weighted global least squares fit was performed. We report the updated molecular constants. The line strengths are based on a recent ab initio calculation of the transition dipole moment function. A line list has been made available, including observed and calculated line positions, Einstein A coefficients and oscillator strengths (f -values). The line list will be useful for astronomers and combustion scientists who utilize C 2 Swan spectra. Einstein A coefficients and f -values were also calculated for the vibrational bands of the Swan system.
A new line list including positions and absolute transition strengths (in the form ofEinstein A values and oscillator strengths) has been produced for the OH ground * Corresponding Author: James Brooke 1 Now at School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK.
Galactic open and globular clusters (OCs, GCs) appear to inhabit separate regions of the age-mass plane. However, the transition between them is not easily defined because there is some overlap between high-mass, old OCs and low-mass, young GCs. We are exploring the possibility of a clear-cut separation between OCs and GCs using an abundance feature that has been found so far only in GCs: (anti)correlations between light elements. Among the coupled abundance trends, the Na-O anticorrelation is the most widely studied. These anticorrelations are the signature of self-enrichment, i.e., of a formation mechanism that implies multiple generations of stars. Here we concentrate on the old, massive, metal-rich OC NGC 6791. We analyzed archival Keck/HIRES spectra of 15 NGC 6791 main sequence turn-off and evolved stars, concentrating on the derivation of C, N, O, and Na abundances. We also used WIYN/Hydra spectra of 21 evolved stars (one is in common). Given the spectral complexity of the very metal-rich NGC 6791 stars, we employed spectrum synthesis to measure most of the abundances. We confirmed the cluster super-solar metallicity and abundances of Ca and Ni that have been derived in past studies. More importantly, we did not detect any significant star-to-star abundance dispersion in C, N, O and Na. Based on the absence of a clear Na-O anticorrelation, NGC 6791 can still be considered a true OC, hosting a single generation of stars, and not a low-mass GC.
Abstract. The eruption of Mt. Tambora in 1815 was the largest volcanic eruption of the past 500 years. The eruption had significant climatic impacts, leading to the 1816 "year without a summer", and remains a valuable event from which to understand the climatic effects of large stratospheric volcanic sulfur dioxide injections. The eruption also resulted in one of the strongest and most easily identifiable volcanic sulfate signals in polar ice cores, which are widely used to reconstruct the timing and atmospheric sulfate loading of past eruptions. As part of the Model Intercomparison Project on the climatic response to Volcanic forcing (VolMIP), five state-of-the-art global aerosol models simulated this eruption. We analyse both simulated background (no Tambora) and volcanic (with Tambora) sulfate deposition to polar regions and compare to ice core records. The models simulate overall similar patterns of background sulfate deposition, alPublished by Copernicus Publications on behalf of the European Geosciences Union.
L. Marshall et al.: Multi-model sulfate deposition from the 1815 Tambora eruptionthough there are differences in regional details and magnitude. However, the volcanic sulfate deposition varies considerably between the models with differences in timing, spatial pattern and magnitude. Mean simulated deposited sulfate on Antarctica ranges from 19 to 264 kg km −2 and on Greenland from 31 to 194 kg km −2 , as compared to the mean ice-corederived estimates of roughly 50 kg km −2 for both Greenland and Antarctica. The ratio of the hemispheric atmospheric sulfate aerosol burden after the eruption to the average ice sheet deposited sulfate varies between models by up to a factor of 15. Sources of this inter-model variability include differences in both the formation and the transport of sulfate aerosol. Our results suggest that deriving relationships between sulfate deposited on ice sheets and atmospheric sulfate burdens from model simulations may be associated with greater uncertainties than previously thought.
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