A dual-wavelength UV-C LED unit, emitting at peaks of 260 nm, 280 nm, and the combination of 260|280 nm together was evaluated for its inactivation efficacy and energy efficiency at disinfecting Escherichia coli, MS2 coliphage, human adenovirus type 2 (HAdV2), and Bacillus pumilus spores, compared to conventional low-pressure and medium-pressure UV mercury vapor lamps. The dual-wavelength unit was also used to measure potential synergistic effects of multiple wavelengths on bacterial and viral inactivation and DNA and RNA damage. All five UV sources demonstrated similar inactivation of E. coli. For MS2, the 260 nm LED was most effective. For HAdV2 and B. pumilus, the MP UV lamp was most effective. When measuring electrical energy per order of reduction, the LP UV lamp was most efficient for inactivating E. coli and MS2; the LP UV and MP UV mercury lamps were equally efficient for HAdV2 and B. pumilus spores. Among the UV-C LEDs, there was no statistical difference in electrical efficiency for inactivating MS2, HAdV2, and B. pumilus spores. The 260 nm and 260|280 nm LEDs had a statistical energy advantage for E. coli inactivation. For UV-C LEDs to match the electrical efficiency per order of log reduction of conventional LP UV sources, they must reach efficiencies of 25-39% or be improved on by smart reactor design. No dual wavelength synergies were detected for bacterial and viral inactivation nor for DNA and RNA damage.

This study examined water quality, naturally-occurring radioactive materials (NORM), major ions, trace metals, and well flow data for water used and produced from start-up to operation of an oil and gas producing hydraulically-fractured well (horizontal) in the Denver-Julesburg (DJ) Basin in northeastern Colorado. Analysis was conducted on the groundwater used to make the fracturing fluid, the fracturing fluid itself, and nine flowback/produced water samples over 220days of operation. The chemical oxygen demand of the wastewater produced during operation decreased from 8200 to 2500mg/L, while the total dissolved solids (TDS) increased in this same period from 14,200 to roughly 19,000mg/L. NORM, trace metals, and major ion levels were generally correlated with TDS, and were lower than other shale basins (e.g. Marcellus and Bakken). Although at lower levels, the salinity and its origin appear to be the result of a similar mechanism to that of other shale basins when comparing Cl/Br, Na/Br, and Mg/Br ratios. Volumes of returned wastewater were low, with only 3% of the volume injected (11millionliters) returning as flowback by day 15 and 30% returning by day 220. Low levels of TDS indicate a potentially treatment-amenable wastewater, but low volumes of flowback could limit onsite reuse in the DJ Basin. These results offer insight into the temporal water quality changes in the days and months following flowback, along with considerations and implications for water reuse in future hydraulic fracturing or for environmental discharge.

The purpose of the study was to separate and identify the unknown surfactants present in flowback and produced water from oil and gas wells in the Denver-Julesburg Basin (Niobrara Formation) in Weld County, Colorado, USA. Weld County has been drilled extensively during the last five years for oil and gas between 7000-8000 feet below land-surface. Polypropylene glycols (PPGs) and polyethylene glycols carboxylates (PEG-Cs) were found for the first time in these flowback and produced water samples. These ethoxylated surfactants may be used as friction reducers, clay stabilizers, and surfactants. Ultrahigh-performance liquid chromatography/quadrupole-time-of-flight mass spectrometry (UHPLC/QTOF-MS) was used to separate and identify the different classes of PPGs, PEG-Cs, and their isomers. The Kendrick mass scale was applied along with mass spectrometry/mass spectrometry (MS-MS) with accurate mass for rapid and unequivocal identification. The PPGs and their isomers occur at the ppm concentration range and may be useful as "fingerprints" of hydraulic-fracturing. Comparing these detections to the compounds used in the fracturing process from FracFocus 3.0 (https://fracfocus.org), it appears that both PPGs and polyethylene glycols (PEGs) are commonly named as additives, but the PEG-Cs have not been reported. The PEG-Cs may be trace impurities or degradation products of PEGs.

A long-term field study (405 days) of a hydraulically fractured well from the Niobrara Formation in the Denver-Julesburg Basin was completed. Characterization of organic chemicals used in hydraulic fracturing and their changes through time, from the preinjected fracturing fluid to the produced water, was conducted. The characterization consisted of a mass balance by dissolved organic carbon (DOC), volatile organic analysis by gas chromatography/mass spectrometry, and nonvolatile organic analysis by liquid chromatography/mass spectrometry. DOC decreased from 1500 mg/L in initial flowback to 200 mg/L in the final produced water. Only ∼11% of the injected DOC returned by the end of the study, with this 11% representing a maximum fraction returned since the formation itself contributes DOC. Furthermore, the majority of returning DOC was of the hydrophilic fraction (60-85%). Volatile organic compound analysis revealed substantial concentrations of individual BTEX compounds (0.1-11 mg/L) over the 405-day study. Nonvolatile organic compounds identified were polyethylene glycols (PEGs), polypropylene glycols (PPG), linear alkyl-ethoxylates, and triisopropanolamine (TIPA). The distribution of PEGs, PPGs, and TIPA and their ubiquitous presence in our samples and the literature illustrate their potential as organic tracers for treatment operations or in the event of an environmental spill.

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Waters produced from fracturing operations in the oil and gas industry are a complex mixture of fracturing fluids and formation water. Closing the water cycle loop in this industry depends on the effective reuse of these wastewaters, and therefore treatment. This study investigated the application of chemical coagulants and powder activated carbon (PAC) to reduce turbidity, dissolved organic carbon (DOC), total petroleum hydrocarbons (TPH), and polyethylene glycols (PEGs) in four hydraulic fracturing wastewaters. Jar tests were performed to evaluate both the PAC and coagulants. Treatment goals were operationally defined targeting 90% reduction of turbidity, PEGs,

Aims: Inactivating microbial contaminants in fresh produce commonly uses chlorine washing. The effectiveness of ozone was explored as an alternative to chlorine in produce washing for ensuring microbial safety while maximizing water reusability. Methods and Results: An ozone washing system was designed to permit continuous addition of contaminated produce and the reuse of washing water. The effectiveness of ozonation (<2 mg l À1 ) was determined using Bacillus subtilis spores as a stricter measure of efficiency with processing time of 10 min. As a comparison, chlorine (c. 100 mg l À1 ) was tested in parallel. Water quality characteristics, including chemical oxygen demand, total suspended solids, disinfectants concentration and microbial reduction were measured. Ozonation showed an average of 1Á56 log reduction of B. subtilis spores on lettuce, while chlorination achieved a 1Á30 log reduction. The effluents after ozonation demonstrated improved water quality, both in physicochemical quality and microbial quality compared to chlorination. Conclusion: Aqueous ozone treatment is effective against microbial contaminants on fresh produce and enables extended use of washing water. Significance and Impact of the Study: The results provide significant data about ozone disinfection efficacy and its impact on the water reusability, which can facilitate the ozone utilization in the fresh produce production as an environmental friendly alternative.