Although the molecular chemistry of thorium is dominated by the +4 oxidation state accounts of Th(iii) complexes have continued to increase in frequency since the first structurally characterised example was reported thirty years ago. The isolation of the first Th(ii) complexes in 2015 and exciting recent Th(iii) and Th(ii) reactivity studies both indicate that this long-neglected area is set to undergo a rapid expansion in research activity over the next decade, as previously seen since the turn of the millennium for analogous U(iii) small molecule activation chemistry. In this perspective article, we review synthetic routes to Th(iii) and Th(ii) complexes and summarise their distinctive physical properties. We provide a near-chronological discussion of these systems, focusing on structurally characterised examples, and cover complementary theoretical studies that rationalise electronic structures. All reactivity studies of Th(iii) and Th(ii) complexes that have been reported to date are described in detail.

In this work, we evaluated the processing and reinforcement characteristics of both carbon black (CB) and graphene nanoplatelets (GNPs) within a nitrile butadiene rubber (NBR) matrix. The aspect ratio of the GNPs was measured using atomic force microscopy (AFM) and related to the dispersion and agglomeration within the NBR matrix, as observed by scanning electron microscopy (SEM). The relationship between GNP aspect ratio and mechanical properties was studied by micromechanical modelling. The tensile and tear properties of NBR after compounding with GNPs were enhanced to a greater extent compared to carbon black, while curing times were smaller and scorch times longer, indicating some of the advantages of using GNPs. Overall, the inherent properties of GNPs along with their geometry led to the production of better-performing rubber compounds that can replace their CB-filled counterparts in applications where flexibility, tear strength and compliance are important. The influence of processing on dispersion, orientation and agglomeration of flakes was also highlighted with respect to the Young’s modulus of the NBR compounds.

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