Motivated by applications of first-order theorem proving to software analysis, we introduce a new inference rule, called subsumption demodulation, to improve support for reasoning with conditional equalities in superposition-based theorem proving. We show that subsumption demodulation is a simplification rule that does not require radical changes to the underlying superposition calculus. We implemented subsumption demodulation in the theorem prover Vampire, by extending Vampire with a new clause index and adapting its multi-literal matching component. Our experiments, using the TPTP and SMT-LIB repositories, show that subsumption demodulation in Vampire can solve many new problems that could so far not be solved by state-of-the-art reasoners.
Today, many essential industrial processes depend on syngas. Due to a high energy demand and overall cost as well as a dependence on natural gas as its precursor, alternative routes to produce this valuable mixture of hydrogen and carbon monoxide are urgently needed. Electrochemical syngas production via two competing processes, namely carbon dioxide (CO2) reduction and hydrogen (H2) evolution, is a promising method. Often, noble metal catalysts such as gold or silver are used, but those metals are costly and have limited availability. Here, we show that metal-organic chalcogenolate assemblies (MOCHAs) combine several properties of successful electrocatalysts. We report a scalable microwave-assisted synthesis method for highly crystalline MOCHAs ([AgXPh] ∞: X = Se, S) with high yields. The morphology, crystallinity, chemical and structural stability are thoroughly studied. We investigate tuneable syngas production via electrocatalytic CO2 reduction and find the MOCHAs show a maximum Faraday efficiency (FE) of 55 and 45% for the production of carbon monoxide and hydrogen, respectively.
Answer Set Programming (ASP) solvers are highly-tuned and complex procedures that implicitly solve the consistency problem, i.e., deciding whether a logic program admits an answer set. Verifying whether a claimed answer set is formally a correct answer set of the program can be decided in polynomial time for (normal) programs. However, it is far from immediate to verify whether a program that is claimed to be inconsistent, indeed does not admit any answer sets. In this paper, we address this problem and develop the new proof format ASP-DRUPE for propositional, disjunctive logic programs, including weight and choice rules. ASP-DRUPE is based on the Reverse Unit Propagation (RUP) format designed for Boolean satisfiability. We establish correctness of ASP-DRUPE and discuss how to integrate it into modern ASP solvers. Later, we provide an implementation of ASP-DRUPE into the wasp solver for normal logic programs.
Metal‐organic frameworks (MOFs) are promising materials for photocatalytic water splitting reactions, but examples of visible light‐responsive, catalytically active, and stable MOFs are still rare. A detailed investigation is conducted for COK‐47 – a recently described MOF comprising 2D Ti‐O6 secondary building units (SBUs) – toward a photocatalytic hydrogen evolution reaction (HER), showing how overall particle morphology, surface area, and missing ligand defects are central parameters governing the material's ultimate performance. The newly synthesized COK‐47ISO is among the most active MOFs to date, yielding HER‐rates of 8.6 µmol h−1, and an apparent quantum yield (AQY) of 0.5% under visible light illumination. Optoelectronic and photoluminescence investigations, supported by theoretical calculations, enable the unraveling of its electronic structure along with charge transfer and recombination kinetics. A wavelength‐dependent reaction mechanism is proposed involving ligand to metal charge transfer (LMCT) and the main challenges for visible or UV photoexcitation are identified, demonstrating that the unique 2D layered structure aids charge separation and is key to the high performance. This work introduces COK‐47 as a promising alternative to the well‐known MIL‐125 family and offers directions for future studies
Amid the COVID-19 pandemic, distance teaching became default in higher education, urging teachers and researchers to revise course materials into an accessible online content for a diverse audience. Probably one of the hardest challenges came with online assessments of course performance, for example by organizing online written exams. In this teaching-related project paper we survey the setting we organized for our master's level course "Automated Deduction" in logic and computation at TU Wien. The algorithmic and rigorous reasoning developed within our course called for individual exam sheets focused on problem solving and deductive proofs; as such exam sheets using test grids were not a viable solution for written exams within our course. We believe the toolchain of automated reasoning tools we have developed for holding online written exams could be beneficial not only for other distance learning platforms, but also to researchers in automated reasoning, by providing our community with a large set of randomly generated benchmarks in SAT/SMT solving and first-order theorem proving.
more recently, also 2D pnictogen compounds have come into focus because of their combination of unusual, potentially useful properties in electronics, energy, and catalysis. [6][7][8][9][10][11][12][13] For the case of bismuth, this includes recent work on binary 2D bismuth oxides, [10][11][12][13] and 2D ternary and multinary oxygen-containing bismuth compound phases, including 2D Bi-oxyhalides, 2D Bi 2 WO 6 , 2D Bi 2 MoO 6 , or 2D BiVO 4 . [2,3,9,14,15] Amongst the ternary bismuth compound phases, the bismuth oxycarbonate (BOC) Bi 2 O 2 CO 3 phase, also called bismutite and bismuth subcarbonate (BiO) 2 CO 3 , is of particular interest. [16] Bi 2 O 2 CO 3 has an intrinsically layered structure composed of alternating Bi 2 O 2 2+ and CO 3 2− sub-layers and is a semiconductor with a band gap of ≈3.1-3.5 eV. [16] In nanostructured form Bi 2 O 2 CO 3 has been shown to have useful properties in particular toward energy, catalysis, and photocatalysis. [16] In particular for photocatalysis, 2D morphology can offer benefits over other morphologies including intrinsically high specific surface areas and short migration lengths of photogenerated charge carriers to the reaction fronts on the 2D materials' surfaces. This can reduce recombination losses and thus lead Laterally large (≈3 µm), atomically thin 2D Bi 2 O 2 CO 3 nanosheets (2D bismuth oxycarbonate, 2D bismutite) are fabricated via sonochemically assisted, template-free synthesis. Keys to the synthesis of the freestanding, laterally large 2D Bi 2 O 2 CO 3 nanosheets from bulk Bi powder are choice of suspension medium, controlled reaction temperatures, and several hours processing time. Lateral sizes of 2D Bi 2 O 2 CO 3 can be controlled between µm-sized nanosheets and tens of nm sized nanoflakes solely based on the choice of suspension medium.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.