Controlling and suppressing the so-called "coffeering effect" (CRE) is an issue of cardinal importance and intense interest in many industries and scientific fields. Here, the combined effect of the particle and surfactant concentration on the CRE is investigated by gradually adding Triton X-100 surfactant to colloidal suspensions of SiO 2 nanoparticles in ethanol for various particle concentrations. First, the effect of particle concentration on the contact line dynamics during the evaporation of a sessile droplet is investigated. It is shown that increasing the particle concentration leads to an increase in pinning time and ring width, whereas the droplet's initial and dynamic contact angle remains unchanged. Afterward, the effect of different concentrations of surfactant is studied for different particle concentrations. It is concluded that the surfactant concentration at which the CRE is suppressed is dependent on the initial particle concentration of the colloid, and it increases as the particle concentration increases. Furthermore, as adding surfactant with a concentration lower than this critical concentration results in an unsuppressed CRE, it is shown that surpassing this concentration will result in a depletion of particles in the contact line. Moreover, it is demonstrated that this critical surfactant concentration has no significant effect on the droplet's geometry and the total evaporation time.

Our discovery reveals the existence of an optimum SDS/CNT concentration ratio to achieve the highest conductivity of ring deposition for strain sensing.

Controllable accumulation of carbon nanotubes in self-assembly techniques is of critical importance in smart patterning and printed electronics. This study investigates how inclining the substrate and inhibiting the droplet spreading...

The passage of a rising air bubble through a stratified horizontal interface between two Newtonian liquids is studied numerically. A ternary phase-field model has been utilized for capturing the interface between three immiscible fluids. According to the previous studies, the density, viscosity, and surface tension of the two liquids, in addition to the bubble diameter, are the effective parameters of bubble interaction with the interface. By changing these variables, three main flow patterns are identified in numerical simulations. Penetration flow regime is observed when the bubble enters the upper liquid alone and does not raise the lower liquid. Entrainment flow regime occurs when the bubble lifts some of the heavier liquid to the lighter liquid but still rises alone. If the bubble holds a film of the denser liquid when it rises in the upper liquid, envelopment flow regime takes place. A flow regime map is represented to distinguish the aforementioned flow patterns using Weber and Morton numbers and determine regime transition criteria based on these two dimensionless parameters. For Weber numbers lower than 30, or Morton numbers higher than 1.7 × 10 −2 , the penetration regime is observed. On the contrary, when the Weber number is higher than 65 and the Morton number is lower than 7 × 10 −5 , the envelopment regime occurs. The entrainment pattern happens between these ranges and two additional limiting relations of 320Mo 0.18 < We < 1500Mo 0.23 .

The circulatory Marangoni flow can alter the contact line deposition in evaporating colloidal droplets with pinned contact line. Marangoni flow can be induced by surfactants or thermal effects. Although both cases have been exclusively investigated, the combined effect of surfactant-induced and thermal Marangoni flows is still unknown. The lattice Boltzmann method is utilized to simulate droplet evaporation and corresponding Marangoni flow. Five equations for hydrodynamics, interface capturing, vapor concentration, temperature field, and surfactant transport are intrinsically coupled with each other. They are simultaneously solved in the lattice Boltzmann framework. A geometrical method is proposed to pin the contact line at the triple point. First, evaporation-induced and thermal Marangoni flows are successfully captured. By incorporating surfactant-induced effects, interesting flow patterns are observed. Considering the combined effect of surfactant and temperature gradient, maximum surfactant concentration and maximum temperature (local minima for surface tension) are found at the top and the edge of the droplet, respectively. The maximum surface tension is consequently located between them, and double-circulation flow is observed. If the thermal effect is eliminated, surfactant local concentrations intermittently converge to steady values so that the edge concentration becomes higher than the apex concentration. Until reaching the steady state, there are two patterns that the flow alternates between: one in the direction of the thermal Marangoni flow and the other in the opposite direction.