We have investigated a uniaxial anisotropy along the [100] direction of GaMnAs film grown on (001) GaAs. The hysteresis observed in the angular dependence of the planar Hall resistance shifted toward the [010] and [010] directions. This phenomenon was analyzed by introducing an additional uniaxial anisotropy field Hu2 along the [100] direction. The magnitude of Hu2 is much smaller than those of the cubic Hc and uniaxial Hu1 anisotropy fields for this material. The temperature behavior of Hu2 appears to be very similar to that of Hu1, suggesting the possibility that Hu1 and Hu2 have a common origin.
High-quality epitaxial thin films of Co-doped anatase TiO2 (Co:TiO2) were grown epitaxially on SrTiO3 (001) substrates by using pulsed laser deposition with in-situ reflection high-energy electron diffraction. The oxygen partial pressure, PO2, during the growth was systematically varied. As PO2 decreased, the growth behavior altered from a two-dimensional layer-by-layer-like growth to a three-dimensional island-like pattern. Electrical conductivity and saturation magnetization increased, seemingly consistent with the picture of carrier-induced ferromagnetism. However, we also found that the spatial distribution of Co ions became highly nonuniform and the chemical state of Co ions changed from ionic to metallic. All of these PO2 dependences, even including the transport and the magnetic properties, can be explained in terms of the formation of cobalt clusters, whose existence was clearly demonstrated by transmission–electron–microscope studies. Our work clearly indicates that the cobalt clustering will result in the room-temperature ferromagnetism observed in our Co:TiO2 films. To check the possible spin polarization of carriers in Co:TiO2 films, we also fabricated a heterojunction composed of a ferromagnetic Co:TiO2, an insulating SrTiO3, and a ferromagnetic half-metallic (La,Ba)MnO3 layer. When the magnetic field was varied, we could not observe any changes in its I–V characteristic curves, which suggests that there might be little spin-polarization effect in the anatase Co:TiO2 layer.
Microbial consortia have been considered potential platforms for bioprocessing applications. However, the complexity in process control owing to the use of multiple strains necessitates the use of an efficient population control strategy. Herein, we report circuit-guided synthetic acclimation as a strategy to improve biochemical production by a microbial consortium. We designed a consortium comprising alginate-utilizing Vibrio sp. dhg and 3-hydroxypropionic acid (3-HP)-producing Escherichia coli strains for the direct conversion of alginate to 3-HP. We introduced a genetic circuit, named “Population guider”, in the E. coli strain, which degrades ampicillin only when 3-HP is produced. In the presence of ampicillin as a selection pressure, the consortium was successfully acclimated for increased 3-HP production by 4.3-fold compared to that by a simple co-culturing consortium during a 48-h fermentation. We believe this concept is a useful strategy for the development of robust consortium-based bioprocesses.
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