Soft
magnetic materials have shown promise in diverse applications
due to their fast response, remote actuation, and large penetration
range for various conditions. Herein, a new soft magnetic composite
material capable of reprogramming its magnetization profile without
changing intrinsic magnetic properties of embedded magnetic particles
or the molecular property of base material is reported. This composite
contains magnetic microspheres in an elastomeric matrix, and the magnetic
microspheres are composed of ferromagnetic microparticles encapsulated
with oligomeric-PEG. By controlling the encapsulating polymer phase
transition, the magnetization profiles of the magnetic composite can
be rewritten by physically realigning the ferromagnetic particles.
Diverse magnetic actuators with reprogrammable magnetization profiles
are developed to demonstrate the complete reprogramming of complex
magnetization profile.
Defect engineering is one of the key technologies in materials science, enriching the modern semiconductor industry and providing good test-beds for solid-state physics. While homogenous doping prevails in conventional defect engineering, various artificial defect distributions have been predicted to induce desired physical properties in host materials, especially associated with symmetry breakings. Here, we show layer-by-layer defect-gradients in two-dimensional PtSe2 films developed by selective plasma treatments, which break spatial inversion symmetry and give rise to the Rashba effect. Scanning transmission electron microscopy analyses reveal that Se vacancies extend down to 7 nm from the surface and Se/Pt ratio exhibits linear variation along the layers. The Rashba effect induced by broken inversion symmetry is demonstrated through the observations of nonreciprocal transport behaviors and first-principles density functional theory calculations. Our methodology paves the way for functional defect engineering that entangles spin and momentum of itinerant electrons for emerging electronic applications.
Heterointerfaces may exhibit unexpected physical properties distinct from intrinsic properties of component materials. In particular, metal–organic interfaces can drive unique interfacial spin moments, which are often called molecular spinterface. Here, van der Waals stacking of molecular layers may lead to variations in the intra/interlayer exchange coupling resulting in multiple ground states, which is highly desired for multifunctional magnetic devices. In this report, the emergence of molecular multispinterface of paramagnetic cobalt‐octaethyl‐porphyrin (CoOEP) layers in a Fe/CoOEP heterostructure is demonstrated through the interfacial layer and a successive antiferromagnetic molecular spin chain. The disentangled interfacial ferromagnetic spins lead to multiple magnetic ground states and behave as additional spin‐dependent scattering centers, as evidenced through the magnetotransport study. In addition, the antiferromagnetic molecule spin chain derives tunable exchange bias, which signifies the dominance of the antiferromagnetic interfacial interaction. Theoretical calculations demonstrate spin configurations of the molecular chain and the antiferromagnetic interfacial coupling through oxygen intermediaries. The development of the molecular multispinterface and controllable exchange bias therein will provide a promising route for the active control of multivalued data processing at the nanoscale.
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