Carbon export out of the surface ocean via the biological pump is a critical sink for atmospheric carbon dioxide. This process transports organic carbon to the deep ocean through sinking particulate organic carbon (POC) and the downward transport of suspended POC and dissolved organic carbon (DOC). Changes in the relative contribution of each pathway can significantly affect the magnitude and efficiency of carbon export to depth. Net community production (NCP), an analog of carbon export under steady state assumptions, is typically estimated using budgets of biologically important chemical tracers in the upper ocean constrained by ship-board or autonomous platform observations. In this study, we use measurements from biogeochemical profiling floats, the Ocean Station Papa mooring, and recently developed algorithms for carbonate system parameters to constrain budgets for three tracers (nitrate, dissolved inorganic carbon, and total alkalinity) and estimate NCP in the Northeast Pacific from 2009 to 2017. Using our multiple-tracer approach, and constraining end-member nutrient ratios of the POC and DOC produced, we not only calculate regional NCP throughout the annual cycle and across multiple depth horizons, but also partition this quantity into particulate and dissolved portions. We also use a particle backscatter-based approach to estimate POC attenuation with depth and present a new method to constrain particle export across deeper horizons and estimate in situ export efficiency. Our results agree well with previously published estimates of regional carbon export annually and suggest that the approaches presented here could be used to assess the magnitude and efficiency of carbon export in other regions of the world's oceans. Plain Language Summary "Carbon export" refers to the amount of carbon dioxide that is removed from the atmosphere by organisms in the surface ocean and subsequently transported into the deep sea, either through sinking particles (more efficient process) or downward mixing (less efficient process), making the ocean a natural sink for atmospheric carbon dioxide and significantly influencing ocean chemistry. The relative proportion of export through each pathway significantly affects the overall efficiency of this process and has implications for the pattern of carbon export globally. Measuring carbon export throughout the year traditionally requires persistent ship-based observations, which can be costly and perilous for researchers. Instead, carbon export is often estimated by budgeting nutrient distributions and changes through time, as they are also controlled by the same processes. These measurements can now be made remotely using autonomous biogeochemical profiling floats. Here, we present a new approach utilizing multiple chemical budgets to estimate carbon export over a decade in the Northeast Pacific, which can be combined to partition export occurring through sinking particles and downward mixing. Our results are supported by previously published estimates of carbon export and sugges...

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We leverage observations from chemical and bio‐optical sensors mounted on a biogeochemical profiling float in the Northeast Pacific Ocean to quantify the cycling and export potential of distinct biogenic carbon pools, including particulate inorganic carbon (PIC), particulate organic carbon (POC), and dissolved organic carbon (DOC). Year‐round observations reveal complex carbon cycle dynamics among these carbon pools. Net DOC production peaked during bloom initiation, about 3 months prior to the summer peak in POC production. We validate the float estimates of DOC cycling with seasonal accumulation and removal rates derived from ship‐board DOC observations over the same period. By combining chemical and bio‐optical tracers of POC cycling, we estimate the instantaneous POC sinking flux (FPOCsinking ${\mathrm{F}}_{{\text{POC}}_{\text{sinking}}}$). The cooccurrence of DOC consumption and POC production and sinking during fall and winter resolves the regional conundrum of a persistent particle sinking flux observed by sediment traps during a season that is known to be heterotrophic. PIC production is small, and uncertainties are large. By combining float‐based estimates of instantaneous net primary production (NPP) and FPOCsinking ${\mathrm{F}}_{{\text{POC}}_{\text{sinking}}}$, we quantify a real‐time carbon export ratio ([FPOCsinking ${\mathrm{F}}_{{\text{POC}}_{\text{sinking}}}$/NPP] × 100%) for the euphotic zone. Elevated export ratios during summer are associated with an increase in the fraction of particles larger than 100 μm in size. Elevated export ratios during winter are associated with the physical redistribution of particles through seasonal deep mixing. Our study demonstrates how the combined use of multiple sensors on biogeochemical profiling floats can provide more nuanced information about upper ocean carbon cycle dynamics.

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Methods commonly used to estimate net primary production (NPP) from satellite observations are now being applied to biogeochemical (BGC) profiling float observations. Insights can be gained from regional differences in float and satellite NPP estimates that reveal gaps in our understanding and guide future NPP model development. We use 7 years of BGC profiling float data from the Northeast Pacific Ocean to quantify discrepancies between float and satellite NPP estimates and decompose them into contributions associated with the platform sensing method and depth resolution of observations. We find small, systematic seasonal discrepancies in the depth‐integrated NPP (iNPP) but much larger (>±100%) discrepancies in depth‐resolved NPP. Annual iNPP estimates from the two platforms are significantly, positively correlated, suggesting that they similarly track interannual variability in the study region. Using the long‐term satellite iNPP record, we identify elevated annual iNPP during two recent marine heatwaves and gain insights about ecosystem functionality.