Sea spray aerosol (SSA) particles were found to be diverse with respect to their molecular composition. The number distribution of the SSA particle ensemble, as defined by the molecular signatures in individual particles, shifted in response to changes in the activity of phytoplankton and bacteria in the seawater. This dynamic shift in the molecular composition of individual SSA particles changes their hygroscopicity, a key climate-relevant property. SUMMARYThe impact of sea spray aerosol (SSA) on climate depends on the size and chemical composition of individual particles that make up the total SSA ensemble. There remains a lack of understanding as to the composition of individual particles within the SSA ensemble and how it changes in response to dynamic ocean biology. Here, we characterize the classes of organic compounds as well as specific molecules within individual SSA particles. The diversity of molecules within the organic fraction was observed to vary between submicrometer-and supermicrometer-sized particles and included contributions from fatty acids, monosaccharides, polysaccharides, and siliceous material. Significant changes in this molecular diversity were observed to coincide with the rise and fall of phytoplankton and heterotrophic bacteria populations within the seawater. Furthermore, the water uptake of individual particles was affected, as learned from studying the hygroscopicity of model systems composed of representative mixtures of salts and organic compounds.

Laws in several U.S. states mandate zero-carbon electricity systems based primarily on renewable technologies, such as wind and solar. Long-term, largecapacity energy storage, such as those that might be provided by power-to-gasto-power systems, may improve reliability and affordability of systems based on variable non-dispatchable generation. Long-term storage can reduce costs of wind-solar-battery electricity systems at current technology costs by filling seasonal and multi-year storage functional roles. Innovation in long-term storage technology could further improve the affordability of reliable renewable electricity.

As reliance on wind and solar power for electricity generation increases, so does the importance of understanding how variability in these resources affects the feasible, cost-effective ways of supplying energy services. We use hourly weather data over multiple decades and historical electricity demand data to analyze the gaps between wind and solar supply and electricity demand for California (CA) and the Western Interconnect (WECC). We quantify the occurrence of resource droughts when the daily power from each resource was less than half of the 39-year daily mean for that day of the year. Averaged over 39 years, CA experienced 6.6 days of solar and 48 days of wind drought per year, compared to 0.41 and 19 for WECC. Using a macro-scale electricity model, we evaluate the potential for both long-term storage and more geographically diverse generation resources to minimize system costs. For wind-solar-battery electricity systems, meeting California demand with WECC generation resources reduces the cost by 9% compared to constraining resources entirely to California. Adding long-duration storage lowers system costs by 21% when treating California as an island. This data-driven analysis quantifies rare weather-related events and provides an understanding that can be used to inform stakeholders in future electricity systems.

Recent studies have shown that sea spray aerosol (SSA) has a size-dependent, complex composition consisting of biomolecules and biologically derived organic compounds in addition to salts. This additional chemical complexity most likely influences the heterogeneous reactivity of SSA, as these other components will have different reactive sites and reaction pathways. In this study, we focus on the reactivity of a class of particles derived from some of the biological components of sea spray aerosol including lipopolysaccharides (LPS) that undergo heterogeneous chemistry within the reactive sites of the biological molecule. Examples of these reactions and the relevant reactive sites are proposed as follows: R-COONa(s) + HNO3(g) → NaNO3 + R-COOH and R-HPO4Na(s) + HNO3(g) → NaNO3 + R-H2PO4. These reactions may be a heterogeneous pathway not only for sea spray aerosol but also for a variety of other types of atmospheric aerosol as well.