Reactions of complexes [MoX{q-C,( CF3)2}2(q-C5Hs)] with certain dienes give the paramagnetic complexes [MoX,(q-diene)(q-C,H,)][diene = 1,3-butadiene, X = CI ( l a ) , Br ( l b ) , or I ( l c ) ; diene = isoprene, X = CI (2); diene = trans-l,3-pentadiene, X = CI (3)] characterised by elemental analysis, i.r. spectroscopy, and mass spectrometry. The structure of (1 a), determined from 2 71 6 observed reflections measured at 185 K and refined to R = 0.0367 (R' = 0.0532), shows a molecule of near Cs symmetry. The cyclopentadienyl ligand is distorted from regular q5 bonding by slippage of the Mo atom across the ring by 0.1 2 A towards q3 co-ordination. The 1,3-butadiene adopts a cis-endo configuration with internal C-C bonds shorter by 0.045 A than terminal C-C bonds; the Mo-C bonds are shorter to terminal than to internal C atoms, and the butadiene is tilted away from a parallel geometry to assume a configuration with Mo which approaches a metallacyclopentene unit. Extended-Huckel molecular orbital (EHMO) calculations on complex (1 a) are presented and confirm the stability of the endo conformation relative to the ex0 form (85 k J mol-'). A by-product in the formation of complex ( l a ) is [Mo,(p-CI) (p3-O){p3-0,~:q2:q2-C4(CF3),}(q-C,H,),], (4)' which has been structurally characterised as its 0.5C,H6 solvate by X-ray diffraction. The structure has been refined t o R = 0.0377 (R' = 0.0488) using 4 21 5 data recorded at 185 K. A flattened isosceles triangle of metal atoms, base ca. 2.90 A, base-apex ca. 2.58 A, is face-capped by 0 and (open) edge-bridged by CI. The C,(CF,), unit is symmetrically bonded to the opposite Mo, face to the capping 0 atom, in a 2 0 + 47t bonding mode. EHMO calculations suggest some multiple character for the base-apex Mo-Mo bonds, but little direct bonding between the basal atoms. Complex ( l a ) is interconverted with TI(SR) into [Mo(SR),(q-C,H,)(q-C,H,)][R = C,H,Me-4 (5a) (72%) or C,F5 (5b) (1 5%)], characterised by analysis and spectroscopy. Cyclic voltammetric studies on complexes ( l a ) , (5a), and (5b) establish a reversible reduction process in both tetrahydrofuran and dichloromethane, and also more complex oxidations. The most easily reduced complex is (5b), whereas (5a) is most readily oxidised. Complexes (1) and (5) all show e.s.r. spectra in solution with hyperfine coupling to 9 5 p 9 7 M ~ and to ligand nuclei of 35r37Cl, 7g*e1Br, and diene terminal 'H atoms. E.s.r. spectra of these complexes in frozen 2-methyltetrahydrofuran are also presented. The e.s.r. results are discussed in relation to the electronic structures of the complexes, especially the nature of the singly occupied molecular orbital, as determined by EH M O calculations on complex (1 a).
Co-ordinatively unsaturated alkyne complexes of the typeJ and corresponding tungsten(I1) species have been the subjects of a number of studies. It has been established that such complexes undergo substitution reactions at ligand X , ' T ~ to form binuclear complexes with alkyne-bridged metal-metal bonds and are attacked at the co-...