The wavelength shift with pressure of the ruby R1 fluorescence line (Δλ) has been calibrated in the diamond-window pressure cell from 0.06 to 1 Mbar. This was done by simultaneously making specific volume measurements of four metals (Cu, Mo, Ag, and Pd) and referring these results to isothermal equations of state derived from shock-wave experiments. The result is P (Mbar) = (19.04/5) {[(λ0+Δλ)/λ0]5−1}, where λ0 is the wavelength measured at 1 bar.
Lithium is found to transform from a body-centered cubic (bcc) to a face-centered cubic (fcc) structure at 6.9 gigapascals (69 kilobars) and 296 kelvin. The relative volume of the bcc structured lithium at 6.9 gigapascals is 0.718, and the fcc structure is 0.25 percent denser. The bulk modulus and its pressure derivative for the bcc structure are 11.57 gigapascals and 3.4, and for the fcc structure are 13.1 gigapascals and 2.8. Extrapolation of the bcc-fcc phase boundary and the melting curve indicate a triple point around 15 gigapascals and 500 kelvin.
Results of a precise determination of the ir absorption strength of H and D in rutile are presented, which permit determination of H or D concentration to an accuracy of 3%. The integrated absorption per ion was (2.51±0.09)×10−17 and (1.33±0.05)×10−17 cm for H and D, respectively. The procedure for calculating the H or D concentration in a particular sample from the ir absorption peaks is illustrated. Used in conjunction with the results of the theoretical analysis of the preceding paper, this technique makes possible the accurate determination of the energy and density of all electron trapping levels in TiO2 crystals. We also describe results showing that heat treatment in a dry H2 atmosphere at ∼800 °C results in the introduction of Ti intersititials but negligible H in the crystal, as predicted by the preceding paper. A technique for measuring diffusion parameters of H and D under conditions of strict chemical equilibrium, thus avoiding the large departures from Fick's law which usually plague such measurements in materials such as TiO2, is also described.
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