The title reactions have been studied at the CCSD(T)/aug-cc-pv∞z level of theory using saddle point geometries at B3LYP/6-311++G(d,p) and MP2/6-311++G(d,p) levels of theory. The reaction endothermicities are in good agreement with current Active Thermochemical Tables values. Theoretical rate constants were estimated using transition state theory. The theoretical rate constants are in good agreement with the present experiments and lower temperature literature data. Over the T range of the present experiments, the theoretically predicted isotope effects are close to unity.