Venus, unlike Earth, is an extremely dry planet although both began with similar masses, distances from the Sun, and presumably water inventories. The high deuterium-to-hydrogen ratio in the venusian atmosphere relative to Earth's also indicates that the atmosphere has undergone significantly different evolution over the age of the Solar System. Present-day thermal escape is low for all atmospheric species. However, hydrogen can escape by means of collisions with hot atoms from ionospheric photochemistry, and although the bulk of O and O2 are gravitationally bound, heavy ions have been observed to escape through interaction with the solar wind. Nevertheless, their relative rates of escape, spatial distribution, and composition could not be determined from these previous measurements. Here we report Venus Express measurements showing that the dominant escaping ions are O+, He+ and H+. The escaping ions leave Venus through the plasma sheet (a central portion of the plasma wake) and in a boundary layer of the induced magnetosphere. The escape rate ratios are Q(H+)/Q(O+) = 1.9; Q(He+)/Q(O+) = 0.07. The first of these implies that the escape of H+ and O+, together with the estimated escape of neutral hydrogen and oxygen, currently takes place near the stoichometric ratio corresponding to water.

[1] Measurements conducted with the Analyzer of Space Plasmas and Energetic Atoms (ASPERA-4) instrument in the Venus Express spacecraft reveal the presence of a plasma transition within a boundary layer that extends along at the flanks of the Venus ionosheath and where the solar wind exhibits changes similar to those reported from previous missions (Mariner 5, Venera, and Pioneer Venus). At the plasma transition there is a sharp downstream decrease in the density of the solar wind electrons and a sudden increase in their temperature embedded within the boundary layer where more gradual changes in the speed, temperature, and density of the solar wind ions are observed. The ASPERA-4 data also show important fluxes of planetary ions measured downstream from the plasma transition and whose dominant velocity component is in the Sun-Venus direction. The speed of those ions is slower than the local solar wind speed and thus is different from that expected from the convective electric field acceleration in which both speed values should be comparable. The boundary layer is interpreted as representing a feature that results from the transport of solar wind momentum to the Venus upper ionosphere, and the ASPERA-4 data provide information on the kinetic properties of the eroded planetary ion population that is seen to stream mostly in the Sun-Venus direction. From the comparison of the ASPERA-4 measurements with those of the magnetic field obtained with the magnetometer of the Venus Express, it is found that in the near wake crossing of the plasma transition the magnetic field intensity decreases to lower values with downstream distance from the planet in agreement with measurements conducted with the Mariner 5 and the PVO. From the analysis of data for orbits with evidence of the plasma transition within the boundary layer, it is found that the momentum flux of planetary ions measured in the wake can be accounted for from the incident momentum flux of the solar wind protons implying an approximate balance as would result from the transport of solar wind momentum to the planetary particles.