Abstract.Asteroids have been used extensively as calibration sources for the Infrared Space Observatory (ISO) and are planned to be used by future groundbased, airborne and space-based projects in the thermal infrared (IR) and in the sub-millimetre. We summarize the general IR observational parameters with a focus on space observatories and discuss brightness variations, apparent velocities and background influences. During the ISO mission ten wellstudied asteroids were used for the photometric calibration of ISOPHOT, but additionally the bright asteroids turned out to be of great interest for many technical tests and calibration aspects. We evaluated the different applications, like testing the photometry of the spectrometers, validation of relative spectral response functions, determination of beam profiles or colour correction tests. The description of the asteroids' thermal emission has been obtained by a recent thermophysical model (TPM). The important model aspects are size, albedo, shape together with the spin vector, a beaming model, thermal inertia and a wavelength-dependent emissivity. With a large sample of observational data provided by three different ISO instruments we had for the first time the possibility to study the thermal emission of several asteroids in detail. The intercomparison between results from different instruments allowed us to distinguish between observational errors and model shortcomings. It turned out that the accuracy of TPM predictions is in many cases strongly related to the limited knowledge of the asteroid shapes. The concepts of beaming, thermal inertia and wavelength dependent emissivities were nicely confirmed for a wide range of observing and illumination geometries under many aspect angles for different asteroids. The TPM predictions for Ceres, Pallas and Vesta are accurate within 5% over the full wavelength range from 5 to 200 µm, for Hygiea and a few other asteroids the predictions and observations agree within 10 to 15%. We found similar emissivity behaviour for the four large asteroids over the full ISO wavelength range. Up to now, no clear spectral features have been seen in the asteroid far-IR spectra.

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