Very large third-order optical nonlinearity, χ(3)∼2.5×10−6 esu, measured by a degenerate four wave mixing method using a short pulse (70 picosecond) laser, has been found in the rapid-thermal annealed Au:SiO2 composite films at concentrations below the Au percolation threshold. The dependence of the χ(3) on Au concentration, p, follows a cubic power law. The maximum figure of merit, χ(3)/α (with α being the absorption coefficient) is about 10−11 esu cm. We explain this result as due to local field enhancement arising from the Mie resonance of the Au nanoclusters, with strong interaction between the nanoclusters further promoting the effect.

Global change has triggered several transformations, such as alterations in climate, land productivity, water resources, and atmospheric chemistry, with far reaching impacts on ecosystem functions and services. Finding solutions to climate and land cover change-driven impacts on our terrestrial environment is one of the most important scientific challenges of the 21st century, with farreaching interlinkages to the socio-economy. The setup of the German Terrestrial Environmental Observatories (TERENO) Pre-Alpine Observatory was motivated by the fact that mountain areas, such as the pre-alpine region in southern Germany, have been exposed to more intense warming compared with the global average trend and to higher frequencies of extreme hydrological events, such as droughts and intense rainfall. Scientific research questions in the TERENO Pre-Alpine Observatory focus on improved process understanding and closing of combined energy, water, C, and N cycles at site to regional scales. The main long-term objectives of the TERENO Pre-Alpine Observatory include the characterization and quantification of climate change and land cover-management effects on terrestrial hydrology and biogeochemical processes at site and regional scales by joint measuring and modeling approaches. Here we present a detailed climatic and biogeophysical characterization of the TERENO Pre-Alpine Observatory and a summary of novel scientific findings from observations and projects. Finally, we reflect on future directions of climate impact research in this particularly vulnerable region of Germany.

Three sorts of probe laser, which have pulse durations of 200 fs, 35 ps, and 70 ps, were employed in the measurement of the third-order nonlinear optical susceptibility x((3)) in Au:SiO(2) composite films in a degenerate four-wave mixing scheme. We found that the composite films at their absorption peak (~550 nm) had a maximum x((3)) , which depends strongly on the pulse width of the probe laser. The value of x((3)) measured with a 70-ps laser was ~30 times larger than that measured with a 200-fs laser. The time-resolved measurements revealed that the optical nonlinearity on the femtosecond time scale is attributable mainly to contributions from the interband electric-dipole transition (especially at low concentrations) and partly to those from hot electrons rather than being dominated by hot-electron excitation in the picosecond regime.

Electrochemical properties of core/branch-structured VS2 nanosheets@CNTs and the in situ investigation of the corresponding dynamic structural evolutions.