~mrnaryThiourea reacts with acetaldehyde and propionaldehyde in acidic media to give condensates in solid state. The nature of these condensates has been investigated with the help of mass and IR spectrometric techniques and a closed chain structures proposed for them.
Thixotropic and self‐healable supramolecular gel with nanohelical morphological features of discotic C3 symmetric benzene‐1,3,5‐tricarboxylic acid coupled with (L)‐ and (D)‐phenylalanine were achieved by hydroxyl anion catalysed methyl ester hydrolysis in presence of lithium ions. The hydrolysis of methyl ester and subsequent formation of gel are highly dependent on metal ions. The arrangement of the molecular building blocks and increasing the structural complexity during the origin of the supramolecular structures from the monomeric units by a chemical reaction act as the executive parameters to determine the handedness of macroscopic chirality.
Thiourea-ammonia-acetaldehyde/propionaldehyde condensate has been obtained. A closed chain triazone structure has been established for it with the help of mass and IR spectrometric studies.
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