In this paper, a broad combined orange-red emission from Eu²⁺- and Eu³⁺-doped low-silica calcium aluminosilicate (LSCAS) glass is reported. Spectroscopic results demonstrate that it is possible to tune the emission wavelength by changing the excitation wavelength in the UV-Vis region. The color coordinates for the emission spectra were calculated, and using the Commission Internationale de l'Éclairage 1931 and 1976 chromatic diagrams, it is possible to note that they are dependent on the excitation wavelength. In addition, the (u', v') color coordinates for the investigated LSCAS samples are close to the Planckian spectrum in the cold region between 2000 and 2600K. Our results show that the Eu:LSCAS system can be used in a white light phosphor when mixed in aggregate with phosphors using green-yellow luminescent ions.

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Photoluminescence quantum yields denote a critical variable to characterise a fluorophore and its potential performance. Their determination, by means of methodologies employing reference standard materials, innevitably leads to large uncertainties....

A dispersive white-light Michelson interferometer was used to determine the wavelength dependence of the refractive index (n) in the visible range from 425 to 775 nm and the thermo-optical coefficient (dn/dT) of fused silica (FS) and borosilicate glass (BK7). For FS, the values obtained for n and dn/dT at 546 nm were 1.46079 and 11.3×10^-6 K^-1, respectively, while the values for BK7 glass were 1.51825 and 2.2×10^-6 K^-1, respectively, which is in good agreement with the literature. The accuracy of the methodology used for n was almost 10^-6, enabling precise spectroscopic characterization of materials across a wide spectral range.

We report a theoretical model and experimental results for laser-induced lensing in solids. The model distinguishes and quantifies the contributions from population and thermal effects. Laser-induced lensing in ytterbium-doped fluorozirconate glass ZBLAN:Yb(3+) is measured, and the thermal and optical properties obtained from analyzing the data with the proposed model agree well with published values. Photothermal techniques are used extensively for the investigation of laser and laser-cooling materials, and the model developed here enables the interpretation of convoluted laser-induced lensing signals that have contributions from different sources.

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