Conventional BCS superconductors are expected to exhibit a conductivity with vanishing dissipation with decreasing temperature. While bulk physical properties measurements indicate PdPb2 is a conventional superconductor with a Tc of 3.0 K, measurements of surface impedance through the microwave cavity perturbation technique indicate a large, non-vanishing dissipative component below Tc that is at odds with conventional superconductivity. We demonstrate PdPb2 to be a possible topological superconductor with a fully gapped bulk and a dissipative Majorana fluid surface.
We investigate the electronic structure of two Ir 5+ honeycomb iridates, Sr3CaIr2O9 and NaIrO3, by means of resonant x-ray techniques. We confirm that Sr3CaIr2O9 realizes a large spin-orbit driven non-magnetic J = 0 singlet ground state despite sizable tetragonal distortions of Ir coordinating octahedra. On the other hand, the resonant inelastic x-ray spectra of NaIrO3 are drastically different from expectations for a Mott insulator with octahedrally coordinated Ir 5+ . We find that the data for NaIrO3 can be best interpreted as originating from a narrow gap non-magnetic S = 0 band insulating ground state. Our results highlight the complex role of the ligand environment in the electronic structure of honeycomb iridates and the essential role of x-ray spectroscopy to characterize electronic ground states of insulating materials.
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