ABSTRACT"Gas-to-liquids" catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-toliquids products are used as transportation fuels and as blendstocks for upgrading crudederived fuels. Methylal(CHs-0-CHz-0-CH& also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than Y diesel fuel, and special precautions for distribution and fuel tank storage are discussed.Steady state engine tests were also performed using an unmodified Cummins 85.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions. Substantial reductions of .particulate matter emissions have been demonstrated 3r IO to 30% blends of methylal in diesel fuel. This research indicates that methylal may be an effective blendstock for diesel fuel provided design changes are made to vehicle fuel handling systems.
This overview will describe briefly key segments of the hydrogen energy cycle from production using various feedstocks to its end use in fuel cells to generate electrical and thermal energy. The paper will also discuss the larger societal context, the so-called "hydrogen economy," in which such production and use of hydrogen may take place. Although most of the public attention on hydrogen has been focused on its potential as an alternative energy source to petroleum and other fossil fuels, a hydrogen economy will encompass much more than a substitution of one energy source by another. Widespread use of hydrogen as an energy carrier can transform our society in much the same way that personal computing technologies have. This transforming power arises from the unique capability of hydrogen to link renewable energy resources and zero-emission energy conversion technologies. Hydrogen can be produced from locally available renewable resources, such as solar, wind, biomass, and water, and converted to electricity or fuel at or near the point of use with only heat and water vapor as "emissions." Hydrogen also lies at the confluence of two emerging trends that will shape our energy future during the first quarter of this century: greater reliance on renewable energy sources and the shift from large, centralized power plants to smaller, decentralized facilities located at or near the point of use. This paper describes these emerging trends and the role of hydrogen in linking them in a way that could transform our society.
The permitting process for hydrogen fueling stations varies from country to country. However, a common step in the permitting process is the demonstration that the proposed fueling station meets certain safety requirements. Currently, many permitting authorities rely on compliance with wellknown codes and standards as a means to permit a facility. Current codes and standards for hydrogen facilities require certain safety features, specify equipment made of material suitable for hydrogen environment, and include separation or safety distances. Thus, compliance with the code and standard requirements is widely accepted as evidence of a safe design. However, to ensure that a hydrogen facility is indeed safe, the code and standard requirements should be identified using a risk-informed process that utilizes an acceptable level of risk. When compliance with one or more code or standard requirements is not possible, a n evaluation of the risk associated with the exemptions to the requirements should be understood and conveyed to the Authority Having Jurisdiction (AHJ). Establishment of a consistent risk assessment toolset and associated data is essential to performing these risk evaluations. This paper describes an approach for risk-informing the permitting process for hydrogen fueling stations that relies primarily on the establishment of risk-informed codes and standards. The proposed risk-informed process begins with the establishment of acceptable risk criteria associated with the operation of hydrogen fueling stations. Using accepted Quantitative Risk Assessment (QRA) techniques and the established risk criteria, the minimum code and standard requirements necessary to ensure the safe operation of hydrogen facilities can be identified. Riskinformed permitting processes exist in some countries and are being developed in others. To facilitate consistent risk-informed approaches, the participants in the International Energy Agency (IEA) Task 19 on hydrogen safety are working to identify acceptable risk criteria, QRA models, and supporting data 1 .
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