Domain structures of unpoled as well as poled (along [001]- and [110]-direction) Pb(Zn1/3Nb2/3)O3 (PZN)-8% PbTiO3 (PT) and Pb(Mg1/3Nb2/3)O3 (PMN)-29% PT single crystals have been investigated by scanning force microscopy (SFM) in the piezoresponse mode, at room temperature. Antiparallel domain structures have been detected mostly in unpoled crystals of both materials, with a fingerprint pattern in (001)-oriented PZN-8% PT crystal. The ferroelastic domain wall has been identified in poled (110)-oriented PZN-8% PT crystal. “Writing” of ferroelectric domains has been performed by applying a dc voltage to the SFM tip. Local re-poling has been observed for all unpoled as well as for poled (001)-oriented crystals at the voltage ±60 V. Local electrical switching was successful in poled (110)-oriented PMN-29% PT at higher voltage (±120 V) but was not successful in poled (110)-oriented PZN-8% PT crystal. Domain-engineered crystals poled in [110]-direction seem to exhibit more stable (in the sense of local re-poling properties) domain arrangement. Hysteretic d(E) dependencies were observed by local application of an ac voltage.
Far-infrared reflectivity spectra of [Pb(Zn1/3Nb2/3)O3]0.92–[PbTiO3]0.08 and [Pb(Mg1/3Nb2/3)O3]0.71–[PbTiO3]0.29 single crystals were investigated between 10 and 530 K, micro-Raman spectra were recorded between 300 and 800 K. No phonon softening was observed near either of the ferroelectric phase transitions. The low-frequency dielectric anomaly in the paraelectric phase is caused by contribution of dynamic polar nanoclusters with the main dispersion in the microwave range. Infrared and Raman spectra confirm the locally doubled unit cell (Zprim=2) in the paraelectric and ferroelectric phases due to the ordering in the perovskite B sites and occurrence of polar nanoclusters in the paraelectric phase. The lowest-frequency transverse optical (TO1) phonon mode active in the infrared spectra is underdamped in contrast to the recent result of inelastic neutron scattering, where no TO1 mode could be observed for the wave vectors q⩽0.2 Å−1. This discrepancy was explained by different q vectors probed in infrared and neutron experiments. The infrared probe couples with very long-wavelength phonons (q≈10−5 Å−1) which see the homogeneous medium averaged over the nanoclusters, whereas the neutron probe couples with phonons whose wavelength is comparable to the nanocluster size (q⩾10−2 Å−1).
The influence of the excitation current on the resonant frequency and its mathematical description makes necessary the introduction of a nonlinear impedance characteristic of the piezoelectric resonator. This influence was modeled by the nonlinear electrical equivalent circuit; the equivalent series resistance and equivalent motional capacitance are taken to be functions of the amplitude of the excitation current by means of the relations derived in the work. The equivalent circuit was analyzed by the method of equivalent linearization. The relationships between the amplitudes of voltage applied on the AT-cut resonator and the first current harmonics or phase-frequency dependence of the excited resonator, respectively, are derived. Amplitude jumps and dynamic temperature change phenomena are discussed.
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