We present a new member of the multiferroic oxides, Lu2MnCoO6, which we have investigated using Xray diffraction, neutron diffraction, specific heat, magnetization, electric polarization, and dielectric constant measurements. This material possesses a net electric polarization strongly coupled to a net magnetization below 35 K, despite the antiferromagnetic ordering of the S = 3/2 Mn 4+ and Co 2+ spins in an ↑↑↓↓ configuration along the c-direction. We discuss the magnetic order in terms of a condensation of domain boundaries between ↑↑ and ↓↓ ferromagnetic domains, with each domain boundary producing an electric polarization due to spatial inversion symmetry breaking. In an applied magnetic field the domain boundaries slide, controlling the size of the magnetization, electric polarization, and magnetoelectric coupling.

A method based on a microemulsion route is presented to obtain magnetic nanoparticles of different sizes, offering several advantages with respect to other similar methods. It consists basically of the development of a microemulsion route above room temperature. Magnetic iron oxide particles with sizes ranging from 2 to 8 nm are obtained. The as-obtained product presents defined X-ray diffraction patterns, without the complications of working in an inert atmosphere or with extra amounts of Fe 2+ , thereby eliminating the need for further steps in order to achieve good crystallization of the material.

We report on the hybrid inorganic-organic ammonium compound [NH4][Cd(HCOO)3], which displays a most unusual framework structure: instead of the expected 4(9)·6(6) topology, it shows an ABX3 perovskite architecture with the peculiarity and uniqueness (among all the up-to-date reported hybrid metal formates) that the Cd ions are connected only by syn-anti formate bridges, instead of anti-anti ones. This change of the coordination mode of the formate ligand is thus another variable that can provide new possibilities for tuning the properties of these versatile functional metal-organic framework materials. The room-temperature crystal structure of [NH4][Cd(HCOO)3] is noncentrosymmetric (S.G.: Pna21) and displays a polar axis. DFT calculations and symmetry mode analysis show that the rather large polarization arising from the off-center shift of the ammonium cations in the cavities (4.33 μC/cm(2)) is partially canceled by the antiparallel polarization coming from the [Cd(HCOO)3](-) framework, thus resulting in a net polarization of 1.35 μC/cm(2). As shown by second harmonic generation studies, this net polarization can be greatly increased by applying pressure (Pmax = 14 GPa), an external stimulus that, in turn, induces the appearance of new structural phases, as confirmed by Raman spectroscopy.

In order to analyze the dynamics of two languages in competition, one approach is to fit historical data on their numbers of speakers with a mathematical model in which the parameters are interpreted as the similarity between those languages and their relative status. Within this approach, we show here, on the basis of a detailed analysis and extensive calculations, the outcomes that can emerge for given values of these parameters. Contrary to previous results, it is possible that in the long term both languages coexist and survive. This happens only when there is a stable bilingual group, and this is possible only if the competing languages are sufficiently similar, in which case its occurrence is favoured by both similarity and status symmetry.