The synthesis and properties of a few dozen highly evolved analogues of (S)-MHPOBC are reported. The liquid crystal phases, and phase transition temperatures and enthalpies, as evidenced by polarized optical microscopy and differential scanning calorimetry, respectively, are given. The helical pitch in pure compounds and some mixtures is estimated using the selective reflection method. All of the compounds show antiferroelectric phases, and some key structure-property relationships for the new materials are reported. Specifically, it is found that the length of the oligomethylene segment of a novel partially fluorinated alkoxy ether tail incorporated into the structures strongly influences the stability of the antiferroelectric phase and the observed phase sequences, as well as the values of the helical pitch and its temperature dependence. The formulation of a family of broad temperature range eutectic mixtures possessing the highly desirable orthoconic antiferroelectric phases with long helical pitch is described.
The design and characterisation of a reconfigurable multi-level spiral phase plate is shown. The device is based on a pie-shape liquid-crystal structure with 24 slices driven by custom electronics that allow independent excitation control of each electrode. The electrooptical cell was manufactured using maskless laser ablation lithography and has shown an unprecedented high fill factor. The topological charge can be dynamically changed between 1, 2, 3, 4, 6, 8 and 12. The device has been calibrated and characterised at 632.8 nm but can be employed at any wavelength in the visible and near infrared spectrum, just modifying the driving parameters of the electrodes. The experimental results have been compared to predictions derived from simulations. An excellent correspondence between theoretical and experimental result has been found in all cases.
Abstract-In recent years, many experimental and theoretical research groups worldwide have actively worked on demonstrating the use of liquid crystals (LCs) as adaptive lenses for image generation, waveform shaping, and non-mechanical focusing applications. In particular, important achievements have concerned the development of alternative solutions for 3D vision. This work focuses on the design and evaluation of the electro-optic response of a LC-based 2D/3D autostereoscopic display prototype. A strategy for achieving 2D/3D vision has been implemented with a cylindrical LC lens array placed in front of a display; this array acts as a lenticular sheet with a tunable focal length by electrically controlling the birefringence. The performance of the 2D/3D device was evaluated in terms of the angular luminance, image deflection, crosstalk, and 3D contrast within a simulated environment. These measurements were performed with characterization equipment for autostereoscopic 3D displays (angular resolution of 0.03°).
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