We present herein the catalytic hydrogenation of various urea derivatives to amines and methanol. The reaction is catalyzed by a ruthenium or an iridium Macho pincer complex and produces amine and methanol in very good to excellent yields. Moreover, we also expand this concept to demonstrate the first example of the hydrogenative depolymerization of polyureas to produce diamines and methanol in moderate yields.
Intelligent Transport Systems (ITS) have a wide range of applications. They range from the more traditional signal coordination system to concepts such as smart cars and smart roads. This paper describes transit‐based ITS measures in Singapore. The island‐state has plans to double the current 90 km rail network over the next ten years and has also implemented or committed to implement many ITS initiatives that impact upon the public transport systems. The aim of these investments is to achieve a high transit modal share using a comprehensive transit network. ITS measures that can promote this aim include: automatic vehicle location systems for buses and taxis, integrated transit fare systems using contactless smart cards, rail information systems, multi‐modal travel guides on Internet and electronic road pricing. The potential impacts of these measures are delay reduction, more comfort, productivity gain and better network accessibility. ITS measures do not necessarily add physical capacity to a public transport system but are excellent supporting measures to encourage the modal shift to transit, particularly if a quality transit system is already in place.
The early warning of incidents on urban arterial roads in a congested city can reduce delay, accidents and pollutant emission. Freeway incident detection systems implemented in recent years may not be suitable for arterial incidents. Arterial incident detection is more difficult. The traffic flow on an arterial road is not conserved from the upstream end of a road link to the downstream end because urban traffic does turn in and out of side‐streets, car‐parks and local residences. Roadside friction such as kerbside parking and shopping traffic also tends to create apparent incidents which are in fact frequent and normal events. This paper develops a definition for an arterial incident and describes a case study on an arterial road in Melbourne, Australia. The study shows that detectors upstream of an incident are more useful for incident detection than downstream detectors. It also identifies occupancy and speed as the appropriate parameters to characterise and detect arterial incidents.
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