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High molecular weight poly(phenylene sulfide−phenyleneamine) (PPSA, M n = 1.5 × 105) was synthesized via a poly(sulfonium) cation through an acid-induced polycondensation reaction of [4-(methylsulfinyl)phenyl]phenylamine. To our best knowledge, the new polymer represents the first hybrid structure of poly(phenylene sulfide) (PPS) and polyaniline (PAni). In contrast to these two intensively studied polymers, PPSA exhibits a high solubility in solvents, such as THF, DMF, DMSO, and NMP. DSC and X-ray studies revealed the completely amorphous structure of PPSA, which cannot even be influenced by annealing the polymer at temperatures above the glass transition. Furthermore, electronic properties were studied by cyclic voltammetry, and preliminary doping experiments for elucidating the electrical conductivity were carried out.

Modern water‐borne paints are applied in different areas ranging from high‐gloss lacquers to flat, scrub‐resistant interior paints. The pigment volume concentration (PVC) is one key‐parameter adjusting the application properties. In this work formulations differing in the type of binder and dispersing agent were investigated by various techniques concerning the distribution of pigments in the liquid paints and films. The structure of the paints was analyzed by Remission Light Spectroscopy (RLS), Disc Centrifugation, Cryo‐Replica Transmission Electron Microscopy (Cryo‐TEM) and Cryo‐Scanning Electron Microscopy (Cryo‐SEM). The pigment distribution in the films was examined by means of Atomic Force Microscopy (AFM), TEM and RLS. The tendency of the pigments to form aggregates was found to depend on both: the type of binder and the dispersing agent. Only by adjusting the properties of the binder in combination with common dispersants it is possible to get well distributed TiO2 particles within the paint. Correlation of application properties e.g. gloss and blocking to the microscopic structure is presented.

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