Sectional views of thin films of symmetric polystyrene/polyisoprene (PS/PI) blends spin-cast from toluene (C6H5CH3) onto CH3- and COOH-terminated self-assembled monolayers (CH3−SAM
and COOH−SAM) show concave- (sharp-edged) and convex-shaped (round) protrusions, respectively, while
other morphology features are identical. A 3-dimensional phase domain arrangement was determined
with spectroscopic techniques (profiling and mapping mode of dynamic secondary ion mass spectrometry,
dSIMS, and X-ray photoelectron spectroscopy). Surface topography was examined with atomic force
microscopy and monitored, during the dSIMS analysis, with secondary electrons. In addition, solvent
evaporation from PS, PI, and PS/PI layers cast on CH3−SAM and COOH−SAM was determined. The
collected data were used to put forward a model of morphology formation and to elucidate the role of
evaporation speed dependent on substrate chemistry in this process, demonstrated here for the first time.
The carboxymethylated derivatives of starch (CMS) and cellulose (CMC) were used for film preparation. The infrared spectroscopy revealed that crosslinking via ester bridges with citric acid occurred between the two polysaccharide derivatives. The effect of polysaccharide derivatives ratio on physicochemical properties of prepared films was evaluated. Generally, the values of tested parameters (moisture absorption, surface roughness, and mechanical and thermal properties) were between the values noted for neat CMS or CMC-based films. However, the physicochemical properties of the system with equal CMS/CMC weight ratio diverged from this trend, i.e., the highest tensile strength, the highest Young’s modulus (ca. 3.4 MPa and ca. 4.9 MPa, respectively), with simultaneously the lowest moisture absorption (18.5% after 72 h) have been noted. Such systems could potentially find application in agriculture or pharmacy.
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