The first X-ray structural determinations of pristine fullerene C(60), cocrystallized 1:1 with corannulene and with its pentaalkyl-substituted derivative, 1,3,5,7,9-penta-tert-butyl-corannulene, have now been achieved.
A procedure is developed to study the evolution of high anisotropy magnetic recording media due to thermally activated grain reversal. It is assumed that the system is composed of single domain grains that evolves by passing through a sequence of relatively long-lived metastable states punctuated by abrupt reversals of individual grains. Solutions to the rate equations describing the sequence of metastable states are calculated using kinetic Monte Carlo. Transition rates are formulated from the Arrhenius-Néel expression in terms of the material parameters, temperature, and applied field. Results obtained from this method are shown to be in good agreement with those calculated from finite-temperature micromagnetics. The method is applied to study the rate dependence of finite-temperature MH loops and the thermal degradation of a recorded bit pattern in perpendicular recording media. A significant advantage of the procedure is its ability to extend simulations over time intervals many orders of magnitude greater than is feasible using standard finite-temperature micromagnetics with relatively modest computational effort.
A Kinetic Monte-Carlo algorithm is applied to examine MH loops of dual-layer magnetic recording media at finite temperature and long time scales associated with typical experimental measurements. In contrast with standard micromagnetic simulations, which are limited to the ns-μs time regime, our approach allows for the direct calculation of magnetic configurations over periods from minutes to years. The model is used to fit anisotropy and coupling parameters to experimental data on exchange-coupled composite media which are shown to deviate significantly from standard micromagnetic results. Sensitivities of the loops to anisotropy, inter-layer exchange coupling, temperature, and sweep rate are examined.
An atomic level micromagnetic model of granular recording media is developed and applied to examine external field-induced grain switching at elevated temperatures which captures non-uniform reversal modes. The results are compared with traditional methods which employ the Landau-Lifshitz-Gilbert equations based on uniformly magnetized grains with assigned intrinsic temperature profiles for M (T ) and K(T ). Using nominal parameters corresponding to high-anisotropy FePt-type media envisioned for Energy Assisted Magnetic Recording, our results demonstrate that atomic-level reversal slightly reduces the field required to switch grains at elevated temperatures, but results in larger fluctuations, when compared to a uniformly magnetized grain model.
The excitation spectra in a stacked square lattice of dipole-exchange coupled classical spins is studied using both standard linearized spin-wave theory and the direct integration of the torque equation. A detailed comparison of the two methods is presented for the case of small-amplitude spin-wave modes. The spin-wave frequencies obtained from the time-dependent correlation functions calculated by integrating the equation of motion are shown to be in excellent agreement with the results obtained from linearized spin-wave theory for both single-layer and multilayer films. Applying the numerical integration method, the finite-temperature correlation function is calculated using Monte Carlo spin dynamics for the case of a single-layer, dipole-exchange coupled system. Values for the frequencies, amplitudes, and decay constant of the spin-wave modes at finite temperature are calculated from a spectral analysis of the finite-temperature correlation function. It is shown that thermal fluctuations give rise to a softening of the spin-wave frequencies and an intrinsic damping of the spin-wave oscillations.
A series of atomistic finite temperature simulations on a model of an FCC lattice of maghemite nanoparticles using the stochastic Landau-Lifshitz-Gilbert (sLLG) equation are presented. The model exhibits a ferromagnetic transition that is in good agreement with theoretical expectations.The simulations also reveal an orientational disorder in the orientational order parameter for T < 0.5T c due to pinning of the surface domain walls of the nanoparticles by surface vacancies. The extent of the competition between surface pinning and dipolar interactions provides support for the conjecture that recent measurements on systems of FCC superlattices of iron-oxide nanoparticles provide evidence for dipolar ferromagnetism is discussed.
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