Soil organic matter (Som) takes part in many environmental functions and, depending on the conditions, it can be a source or a sink of the greenhouse gases. Presently, the changes in soil organic carbon (SoC) stock can arise because of the climatic changes or changes in the land use and land management. A promising method in the estimation of SoC changes is modelling, one of the most used models for the prediction of changes in soil organic carbon stock on agricultural land being the rothC model. Because of its simplicity and availability of the input data, rothC was used for testing the efficiency to predict the development of SoC stock during 35-year period on agricultural land of Slovakia. The received data show an increase of SoC stock during the first (20 years) phase and no significant changes in the course of the second part of modelling. The increase of SoC stock in the first phase can be explained by a high carbon input of plant residues and manure and a lower temperature in comparison with the second modelling part.
Tobiašová E., Barančíková G., Gömöryová E., Makovníková J., Skalský R., Halas J., Koco Š., Tarasovičová Z., Takáč J., Špaňo M. Soil organic matter (SOM) plays an important role in the soil aggregation and vice versa, its incorporation into the soil aggregates is one of the mechanisms of soil organic carbon stabilization. In this study the influence of labile carbon fractions on the fractions of dry-sieved (DSA) and wet-sieved (WSA) macro-aggregates and the relationship between the content of total organic carbon (TOC) and its labile fractions in the soil and in the fractions of macro-aggregates were determined. The experiment included six soil types (Eutric Fluvisol, Mollic Fluvisol, Haplic Chernozem, Haplic Luvisol, Eutric Cambisol, Rendzic Leptosol) in four ecosystems (forest, meadow, urban, and agro-ecosystem). In the case of DSA, the contents of labile fractions of carbon, in particular cold water extractable organic carbon (CWEOC) and hot water extractable organic carbon (HWEOC), had a higher impact on the proportions of larger fractions of macro-aggregates (3-7 mm), while in the case of WSA, the impact of labile fractions of carbon, mainly labile carbon (C L ) oxidizable with KMnO 4 , was higher on the proportions of smaller fractions of aggregates (0.25-1 mm). The WSA size fraction of 0.5-1 mm seems an important indicator of changes in the ecosystems and its amounts were in a negative correlation with C L (r = -0.317; P < 0.05) and HWEOC (r = -0.356; P < 0.05). In the WSA and DSA size fractions 0.5-1 mm, the highest variability in the contents of TOC and C L was recorded in the forest ecosystem > meadow ecosystem > urban ecosystem > agro-ecosystem. The higher were the inputs of organic substances into the soil, the greater was the variability in their incorporation into the soil aggregates. The influence of the content of TOC and its labile forms on their contents in the DSA and WSA was different, and the contents of TOC and C L in the aggregates were more significantly affected by the C L content than by water soluble carbon. In the case of WSA fractions, their carbon content was more affected in the 1-2 mm than in 0.5-1 mm fraction.
The direction of changes and conversion of soil organic carbon (SOC) is in most current ecosystems influenced by human activity. Soil Science and Conservation Research Institute is responsible for monitoring the agricultural soils in a five-year cycle. One part of the soil monitoring involves the determination of the soil organic carbon (SOC) storage. Further, we followed the conversion of arable land on grassland during more than 20 years of monitoring period at some locations where changes in land use occurred. Ten places on basic network and 2 places on key monitoring localities in which arable land have been converted into grassland were identified. About 50 percent of studied soils converted into permanent grassland were Cambisols. The other converted soil types were Luvic Stagnosol, Stagnic Regosol, Mollic Fluvisol, and Stagnic Luvisol. The results showed that after the third monitoring cycle (2002), increase of SOC was observed in all the localities, with the change in land use. Statistical parameter (t-test) confirmed significant differences between the set of average SOC values before and after the land use conversion. The chemical structure of humic acids (HA) isolated from arable soil and permanent grassland indicated increasing of aliphatic carbon content in grassland HA. More aromatic and stabile were HA isolated from arable soils.
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