The influence of surface properties on the flow of fluids, including epoxy resin, through aligned glass and other fiber beds has been examined. The observed flow rates were higher than those predicted from the Kozeny‐Carman equation, and were influenced by the surface properties of the fluid used. This is attributed to variations in the distribution of porosities and to the presence of air bubbles trapped during the initial wetting of the bed. The implications of these findings to the preparation of composites are discussed.
Purpose: To develop a physical understanding of ureterorenoscopy irrigation, we derive mathematical models from basic physical principles and compare these predictions with the results of benchtop experiments. Mathematical modeling can be used to understand the role of inlet pressure, tip deflection, the presence of working tools, geometric properties of the instruments used, and material properties of the irrigation fluid on resulting flow rate.Materials and Methods: We develop theoretical models to describe irrigation flow in an idealized setup and compare with benchtop experiments for flow through a straight scope, a scope with a deflected tip, and a scope with a working tool inserted. The benchtop experiments were performed using Boston Scientific LithoVue ureteroscope and a variety of Boston Scientific working tools. Standard ureteroscope working channels have circular cross sections, but using theoretical models we investigate whether modifications to the cross-sectional geometry can enhance flow rates.Results: The theoretical flow predictions are confirmed by experimental results. Tip deflection is shown to have a negligible effect on flow rate, but the presence of working tools decreases flow significantly (for a fixed driving pressure). Flow rate is predicted to improve when tools are placed at the edge of the channel, rather than the center, and modifying the cross-sectional shape from a circle to an ellipse can further increase flow rate.Conclusions: A mathematical framework is formulated and shown to accurately predict the properties of ureteroscope irrigation flow. The theoretical approach has significant potential in quantifying irrigation flow and improving ureteroscope design.
SynopsisEight epoxy-diamitie networks have beeii formed, diamineb wilh 2 to 12 methyleiie groups being used as curing agents. Dynamic mechanical tests revealed foiir transitioti regions in the dynamic loss modulus/temperature relatioriship. Two possible explaiiatioris for the relaxation of the glycidyl portion of the structure are proposed. One of the relaxations could be due to the breakdown of hydrogen bonds through the hydroxyl and ether groups. The second could be ascribed to the relaxation of the unbonded glycidyl groups or a second relaxation of the glycidyl groups after the breakdown of the hydrogen bonds.
EXPERIMENTALEight epoxy-diamine networks have been formed. The epoxy resin used was pure 2,2-bis (4'-glycidyl phenyl ether) propane, mp 43.5"C, obtained by solvent/nonsolvent precipitation of Shell Epikote 828. CH, 2,2-bis(4 -glycidyl plieiiyl e(,lier) propuic Laminex Indurtrie,s,
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