The evolution of recycling behaviour has been investigated during long pulse discharges in the HT-7 tokamak after ICRF boronization (C2B10H12) using the H/(H+D) ratio and the edge recycling coefficient R. After boronization, impurity reduction is observed, attributed to the fresh boron film, but the recycling coefficient can exceed unity due to a large amount of hydrogen absorbed in the film, leading to an uncontrollable density rise and discharge termination. When the H/(H+D) ratio was reduced to less than 25%, the electron density was easily controlled. The longest discharge, up to 240 s with central electron temperature Te(0) of about 1.0 keV and central electron density ne(0) of 0.8 × 1019 m−3, was achieved following boronization. After many discharges the effectiveness of boron film was weakened, and the density rise was correlated with an increase in both carbon and oxygen radiation which limited the duration of long pulse discharges.