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Atmospheric carbon dioxide concentrations and climate are regulated on geological timescales by the balance between carbon input from volcanic and metamorphic outgassing and its removal by weathering feedbacks; these feedbacks involve the erosion of silicate rocks and organic-carbon-bearing rocks. The integrated effect of these processes is reflected in the calcium carbonate compensation depth, which is the oceanic depth at which calcium carbonate is dissolved. Here we present a carbonate accumulation record that covers the past 53 million years from a depth transect in the equatorial Pacific Ocean. The carbonate compensation depth tracks long-term ocean cooling, deepening from 3.0-3.5 kilometres during the early Cenozoic (approximately 55 million years ago) to 4.6 kilometres at present, consistent with an overall Cenozoic increase in weathering. We find large superimposed fluctuations in carbonate compensation depth during the middle and late Eocene. Using Earth system models, we identify changes in weathering and the mode of organic-carbon delivery as two key processes to explain these large-scale Eocene fluctuations of the carbonate compensation depth.

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This paper summarizes the biostratigraphy and magnetostratigraphy of the 11 sites drilled on the Kerguelen Plateau and in Prydz Bay, Antarctica, during ODP Leg 119. Excellent magnetobiochronologic reference sections were obtained at deep-water Sites 745 and 746 (0-10 Ma) and at intermediate depth Site 744 (0-39 Ma) on the southern Kerguelen Plateau. Site 738, an intermediate depth companion site for Site 744, contains a nearly complete lowermost Oligocene to Turonian carbonate section including a continuous sequence across the Cretaceous/Tertiary boundary. Northern Kerguelen Sites 736 and 737 (ca. 600 m water depth) constitute a composite middle Eocene to Quaternary reference section near the present-day Antarctic Polar Front. Biostratigraphic control is limited in Prydz Bay Sites 739-743. Glacial sequences cored on the continental shelf at Sites 739 and 742 appear to form a composite record, possibly from the uppermost middle Eocene to the Quaternary; the entire upper Oligocene and most of the Miocene, however, are removed at an unconformity. Preglacial sediments at Site 741 contain Early Cretaceous pollen and spores, but the red beds cored at Site 740 are unfossiliferous. Poorly-fossiliferous glacial sediments of probable Quaternary age were sampled on the upper slope at Site 743. A magnetobiochronologic time scale is presented for the Late Cretaceous and Cenozoic of the Southern Ocean based on previous studies and the results of Leg 119 studies.

Samples were examined for diatoms from 22 holes at 11 sites cored by ODP Leg 119 on the Kerguelen Plateau and in Prydz Bay, East Antarctica. Diatoms were observed in Oligocene through Holocene sediments recovered from the Kerguelen Plateau. The diatom flora from the Kerguelen Plateau is characterized by species such as Azpeitia oligocenica, Rocella gelida, Rocella vigilans, and Synedra jouseana in the Oligocene and Crucidenticula nicobarica, Denticulopsis hustedtii, Nitzschia miocenica, and Thalassiosira miocenica in the Miocene. This somewhat cosmopolitan assemblage gives way to a Pliocene and Holocene assemblage characterized by species such as Nitzschia kerguelensis, Thalassiosira inura, and Thalassiosira torokina, which are endemic to the Southern Ocean region. Samples examined from Prydz Bay are generally devoid of diatoms. The exception is Site 739, where diatoms occur sporadically in lower Oligocene and upper Miocene through Quaternary sediments.The Leg 119 diatom biostratigraphic results allow the development of a stratigraphic framework for the Indian sector of the Southern Ocean. This diatom zonation integrates diatom zonations developed previously for other sectors of the Southern Ocean. The zonation proposed here is based on biostratigraphic events of both geographically widespread and endemic species calibrated to the paleomagnetic stratigraphy. As such, this zonation has application throughout the Southern Ocean and allows correlation from the southern high latitudes to the low latitudes.