Victor von Richter in 1871-1875 reported (1, 2, 3) the reaction of p-nitrobromobenzene with alcoholic potassium cyanide to give m-bromobenzoic acid, together with some equally odd reactions of other nitrohalobenzenes with the same reagent. This paper presents experimental confirmation of some of these reports, improvements in the experimental procedure, and investigations of the behavior of additional aromatic nitro compounds with alcoholic potassium cyanide. We believe that we are dealing with a general reaction of aromatic nitro compounds, and present our ideas on its mechanism.It is remarkable that in the three-quarters of a century elapsed since von Richter's4 papers, only Holleman (4) has done further work on the same sort of reaction. In Table I Holleman's results are displayed along with von Richter's. COOH
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.