The formation of covalent bonds to single-walled carbon nanotube (SWNT) or graphene surfaces usually leads to a decrease in the electrical conductivity and mobility as a result of the structural rehybridization of the functionalized carbon atoms from sp(2) to sp(3). In the present study, we explore the effect of metal deposition on semiconducting (SC-) and metallic (MT-) SWNT thin films in the vicinity of the percolation threshold and we are able to clearly delineate the effects of weak physisorption, ionic chemisorption with charge transfer, and covalent hexahapto (η(6)) chemisorption on these percolating networks. The results support the idea that for those metals capable of forming bis-hexahapto-bonds, the generation of covalent (η(6)-SWNT)M(η(6)-SWNT) interconnects provides a conducting pathway in the SWNT films and establishes the transition metal bis-hexahapto organometallic bond as an electronically conjugating linkage between graphene surfaces.

The conformational states of a semiflexible polymer enclosed in a compact domain of typical size a are studied as stochastic realizations of paths defined by the Frenet equations under the assumption that stochastic "curvature" satisfies a white noise fluctuation theorem. This approach allows us to derive the Hermans-Ullman equation, where we exploit a multipolar decomposition that allows us to show that the positional probability density function is well described by a Telegrapher's equation whenever 2a/ p > 1, where p is the persistence length. We also develop a Monte Carlo algorithm for use in computer simulations in order to study the conformational states in a compact domain. In addition, the case of a semiflexible polymer enclosed in a square domain of side a is presented as an explicit example of the formulated theory and algorithm. In this case, we show the existence of a polymer shape transition similar to the one found by Spakowitz and Wang [Phys. Rev. Lett. 91, 2 (2003)] where in this case the critical persistence length is * p a/8 such that the mean-square end-to-end distance exhibits an oscillating behavior for values p >

A brief review of the string percolation model and its results are presented together with the comparison to experimental data. First, it is done an introduction to the quark-gluon phase diagram and the lattice results concerning the connement and the percolation of center domains. It is studied the interaction of the strings produced in nucleus-nucleus and proton-proton collisions showing how the string percolation arises. The main consequences of the string percolation, concerning the dependence on the energy and centrality, on the multiplicities and the mean transverse momentum are obtained comparing with experimental data. It is emphasized the non-abelian character of the color eld of the strings forming the cluster to reproduce the rise of the transverse momentum with multiplicity and the relative suppression of multiplicities. It is also studied dierent observables like multiplicity and transverse momentum distributions, dependence with multiplicity and transverse momentum correlations, forward-backward correlations, the strength of the Bose-Einstein correlations, dependence on the multiplicity of J/ψ  production and its possible suppression in pp collisions at high multiplicity, strangeness enhancement, elliptic ow, and ridge structure. The comparison with the data shows an overall agreement. The thermodynamical properties of the extended cluster formed in the collision are discussed computingits energy and entropy density, shear viscosity over entropy density ratio, bulk viscosity, sound speed and trace anomaly as a function of temperature, showing a remarkable agreement with lattice QCD evaluations. The string percolation can be regarded as the initial frame able to describe the collective behavior produced in AA and pp collisions.

It has been shown that a hot and dense deconfined nuclear matter state produced in ultra-relativistic heavy-ion collisions, can be quantitatively described by the String Percolation phenomenological model. The model address the phase transition in terms of the two-dimensional continuum percolation theory over strings, which are schematic representations of the fundamental interactions among the partons of the colliding nuclei in the initial state. In this work, we present an extension of the critical string density results including the eccentricity dependence on the initial state geometry focus on small string number with different density profile, small deviations from the different profile densities are found. The percolation threshold shows consistency with the thermodynamic limit for the uniform density profile with a large number of strings in the case of circular boundary system. A significant dependence on the eccentricity for a small number of strings compared to high occupancy systems is exhibited, the implications may become relevant in hadron-hadron or hadron-nucleus collision systems.

We report a formula for the dry adiabatic lapse rate that depends on the compressibility factor and the adiabatic curves. Then, to take into account the nonideal behavior of the gases, we consider molecules that can move, rotate, and vibrate and the information of molecular interactions through the virial coefficients. We deduce the compressibility factor in its virial expansion form and the adiabatic curves within the virial expansion up to any order. With this information and to illustrate the mentioned formula, we write the lapse rate for the ideal gas, and the virial expansion up to the second and third coefficient cases. To figure out the role of the virial coefficients and vibrations, under different atmospheric conditions, we calculate the lapse rate for Earth, Mars, Venus, Titan, and the exoplanet Gl 581d. Furthermore, for each one we consider three models in the virial expansion: van der Waals, square-well, and hard-sphere. Also, when possible, we compare our results to the experimental data. Finally, we remark that for Venus and Titan, which are under extreme conditions of pressure or temperature, our calculations are in good agreement with the observed values, in some instances.

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We study the effect of the second virial coefficient on the adiabatic lapse rate of a dry atmosphere. To this end, we compute the corresponding adiabatic curves, the internal energy, and the heat capacity, among other thermodynamic parameters. We apply these results to Earth, Mars, Venus, Titan, and the exoplanet G1 851d, considering three physically relevant virial coefficients in each case: the hardsphere, van der Waals, and the square-well potential. These examples illustrate under which atmospheric conditions the effect of the second virial coefficient is relevant. Taking the latter into account yields corrections towards the experimental values of the lapse rates of Venus and Titan in some instances.