We report the detection of 10–30 parts-per-trillion levels of pentaerythritol tetranitrate and hexahydro-1,3,5-triazine within 20 s of exposure to a silicon microcantilever with its gold surface modified with a self-assembled monolayer of 4-mercaptobenzoic acid. These measurements correspond to a limit of detection of a few fg.

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We report the development of a handheld sensor based on piezoresistive microcantilevers that does not depend on optical detection, yet has high detection sensitivity. The sensor is able to detect vapors from the plastic explosives pentaerythritol tetranitrate and hexahydro-1,3,5-triazine at levels below 10 parts per trillion within few seconds of exposure under ambient conditions. A differential measurement technique has yielded a rugged sensor that is unaffected by vibration and is able to function as a “sniffer.” The microelectromechanical system sensor design allows for the incorporation of hundreds of microcantilevers with suitable coatings in order to achieve sufficient selectivity in the future, and thus could provide an inexpensive, unique platform for the detection of chemical, biological, and explosive materials.

We measured the adsorption of water vapor and trinitrotoluene (TNT) on a silicon cantilever that was coated with a self-assembled monolayer (SAM) of 4-mercaptobenzoic acid on one surface. Even though hydrogen bonding is responsible for adsorption in both cases, the adsorption characteristics were quite different for the two species. In the case of water vapor, the mass loading and bending both increased with relative humidity in a linear fashion. For TNT in the dry nitrogen carrier, the mass loading and bending initially increased rapidly and then leveled off around one monolayer of coverage irrespective of the TNT concentration. This study shows that microcantilevers provide a convenient and versatile platform for the monitoring of molecular binding to SAMs. LA034969N

Surface stress induced by molecular adsorption in three different binding processes has been studied experimentally using a microcantilever sensor. A comprehensive free-energy analysis based on an energy conservation approach is proposed to explain the experimental observations. We show that when guest molecules bind to atoms/molecules on a microcantilever surface, the released binding energy is retained in the host surface, leading to a metastable state where the excess energy on the surface is manifested as an increase in surface stress leading to the bending of the microcantilever. The released binding energy appears to be almost exclusively channeled to the surface energy, and energy distribution to other channels, including heat, appears to be inactive for this micromechanical system. When this excess surface energy is released, the microcantilever relaxes back to the original state, and the relaxation time depends on the particular binding process involved. Such vapor phase experiments were conducted for three binding processes: physisorption, hydrogen bonding, and chemisorption. Binding energies for these three processes were also estimated.

The infrared-active (IR) vibrational mode of ethanol (EtOH) associated with the asymmetrical stretching of the C-C-O bond in pico-liter volumes of EtOH-water binary mixtures is calorimetrically measured using photothermal microfluidic cantilever deflection spectroscopy (PMCDS). IR absorption by the confined liquid results in wavelength dependent cantilever deflections, thus providing a complementary response to IR absorption revealing a complex dipole moment dependence on mixture concentration. Solvent-induced blue shifts of the C-C-O asymmetric vibrational stretch for both anti and gauche conformers of EtOH were precisely monitored for EtOH concentrations ranging from 20–100% w/w. Variations in IR absorption peak maxima show an inverse dependence on induced EtOH dipole moment (μ) and is attributed to the complex clustering mechanism of EtOH-water mixtures.

A method of power transmission is proposed that delivers power through the resonance of a helical receiver with its surrounding stray capacitance. The system operates in a quasi-wireless state where power is transferred over a single connection to a surface much larger than the dimensions of the receiver. This ensures high-efficiency energy transfer over large areas without the need of strong coupling electromagnetic fields. Standard power connectors such as tracks, plugs, and cords may be easily replaced with conductive surfaces or objects such as foil sheets, desks, and cabinets. Presently, the method is experimentally demonstrated at the small scale using loads of up to 50 W at an efficiency of 83% with both bare and insulated surfaces. Simple circuit modeling of the system is presented which shows close agreement with experimental results.

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